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natali 33 [55]
3 years ago
13

The tabulated data were collected for this reaction:

Chemistry
1 answer:
erastovalidia [21]3 years ago
3 0

Answer:

ai) Rate law,  Rate = k [CH_3 Cl] [Cl_2]^{0.5}

aii) Rate constant, k = 1.25

b) Overall order of reaction = 1.5

Explanation:

Equation of Reaction:

CH_{3} Cl (g) + 3 Cl_2 (g) \rightarrow CCl_4 (g) + 3 HCl (g)

If A + B \rightarrow C + D, the rate of backward reaction is given by:  

Rate = k [A]^{a} [B]^{b}\\k = \frac{Rate}{ [A]^{a} [B]^{b}}\\k = \frac{Rate}{ [CH_3 Cl]^{a} [Cl_2]^{b}}

k is constant for all the stages

Using the information provided in lines 1 and 2 of the table:

0.014 / [0.05]^a [0.05]^b = 00.029/ [0.100]^a [0.05]^b\\0.014 / [0.05]^a [0.05]^b = 00.029/ [2*0.05]^a [0.05]^b\\0.014 / = 0.029/ 2^a\\2^a = 2.07\\a = 1

Using the information provided in lines 3 and 4 of the table and insering the value of a:

0.041 / [0.100]^a [0.100]^b = 0.115 / [0.200]^a [0.200]^b\\0.041 / [0.100]^a [0.100]^b = 0.115 / [2 * 0.100]^a [2 * 0.100]^b\\

0.041 = 0.115 / [2 ]^a [2]^b\\ \[[2 ]^a [2]^b = 0.115/0.041\\ \[[2 ]^a [2]^b = 2.80\\\[[2 ]^1 [2]^b = 2.80\\\[[2]^b = 1.40\\b = \frac{ln 1.4}{ln 2} \\b = 0.5

The rate law is: Rate = k [CH_3 Cl] [Cl_2]^{0.5}

The rate constant k = \frac{Rate}{ [CH_3 Cl]^{a} [Cl_2]^{b}} then becomes:

k = 0.014 / ( [0.050] [0.050]^(0.5) )\\k = 1.25

b) Overall order of reaction =  a + b

Overall order of reaction = 1 + 0.5

Overall order of reaction = 1.5

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C6H5COOH+ CN-= C6H5COO- + HCN

Explanation:

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C6H5COOH + Na+ + CN- = C6H5COO- + Na+ + HCN

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3 years ago
Which statement is true for a solution when its concentration of hydroxide ions increases? It becomes more acidic. It becomes le
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Its pH value increases.

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The compound dioxane, which is used as a solvent in various industrial processes is composed of C,H, and O atoms. Combustion of
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Answer:

The correct formula of dioxane is C₄H₈O₂.

Explanation:

Given data:

mass of dioxane= 2.23 g

mass of water = 1.802 g

mass of carbon dioxide = 4.401 g

molar mass of dioxane = 88.1 g / mol

Molecular formula of dioxane = ?

Solution:

percentage of carbon = (4.401 g/2.23 g ) × (12 /44) × 100

                                     =  (1.98 × 0.273) × 100 = 54.1

percentage of hydrogen =  (1.802 g/ 2.23 g) × (2.016 /18.016) × 100

                                         = (0.81 × 0.112) × 100 = 9.072

percentage of oxygen = 100 - (54.1 + 9.072)

                                     = 100 - 63.172 = 36.828

Now we will determine the number of grams atoms of carbon, hydrogen and oxygen.

No. of gram atoms of carbon = 54.1 /12 = 4.51

No. of gram atoms of hydrogen = 9.072 / 1.008 = 9

No. of gram atoms of oxygen = 36.828 / 16 = 2.302

Atomic ratio:

    C :H :O               4.51/ 2.302    :   9 / 2.302   :  2.302 /2.302

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Molecular formula:

   Molecular formula = n × (empirical formula)

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    empirical formula mass= 24+ 4.032 +16 = 44.032

                 n = 88.1 / 44.032 = 2

        Molecular formula = n × (empirical formula)

        Molecular formula = 2 × (C₂H₄O)

         Molecular formula = C₄H₈O₂

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Answer:

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