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Valentin [98]
3 years ago
6

A ridged steel tank filled with 62.7L of nitrogen gas of 85.0L atm

Chemistry
1 answer:
mylen [45]3 years ago
8 0

The final gas pressure : 175.53 atm

<h3>Further explanation</h3>

Maybe the complete question is like this :

A ridged steel tank filled with 62.7 l of nitrogen gas at 85.0 atm and 19 °C is heated to 330 °C while the volume remains constant. what is the final gas pressure?

The volume remains constant⇒Gay Lussac's Law  

<em>When the volume is not changed, the gas pressure in the tube is proportional to its absolute temperature  </em>

\tt \dfrac{P_1}{T_1}=\dfrac{P_2}{T_2}

P₁=85 atm

T₁=19+273=292 K

T₂=330+273=603 K

\tt P_2=\dfrac{P_1\times T_2}{T_1}\\\\P_2=\dfrac{85\times 603}{292}\\\\P_2=175.53~atm

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Explanation:

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Starting with 250 mL of a 0.250 M solution of HBr; a) Calculate the initial pH of the solution.b) Calculate the pH after adding
maxonik [38]

Answer:

a.

pH =  0.602

b.

pH = 1.5

c.

pH = 7

d.

pH = 12.1

Explanation:

a ) To calculate the pH, use the following equation:

pH = -log [H+]

Hbr is a strong acid, so the [H+] concentration can be calculated as follow:

[HBr] = 0.250 M

As acid Hbr:

Hbr = H+ + Br-

As strong acid HBr dissociates at all, so

[HBr] = [H+] = 0.250 M

So the pH:

<u>pH = -log [0.250 M] = 0.602</u>

<u></u>

<u>b) Calculate the pH after adding 250 mL of 0.125M NaOH</u>

<u></u>

<u>I</u>n this point, the reactions starts:

<u></u>

HBr + NaOH = H2O + NaBr

- First, we gonna find the mol of each reactant:

HBr:

mol = [M] × L

mol = 0.250 M × 0.250 L

mol = 0.0625 mol HBr

NaOH:

mol = [M] × L

mol = 0.125 M × 0.250L

mol = 0.03125 mol NaOH

In base on the reaction, it’s needed 1 mol of NaOH to neutralize 1 mole of HBr, so to neutralize 0.0625 moles of HBr its needed 0.0625 mol of NaOH:

0.0625 mol HBr – 0.03125 mol HBr = 0.03125 mol HBr

These are the moles free in the solution, and we going to use them to calculate the pH:

pH = -log [ H]

pH = - log [ 0.03125 ] = 1.5

<u>c) Calculate the pH after adding 500 mL of 0.125M NaOH</u>

NaOH:

mol = [M] × L

mol = 0.125 M × 0.500L

mol = 0.0625 mol NaOH

In base on the reaction, it’s needed 1 mol of NaOH to neutralize 1 mole of HBr, so to neutralize 0.0625 moles of HBr its needed 0.0625 mol of NaOH:

0.0625 mol HBr – 0.0625 mol HBr = 0 HBr

pH = 7

<u>d) Calculate the pH after adding 600 mL of 0.125M NaOH.</u>

<u>NaOH:</u>

mol = [M] × L

mol = 0.125 M × 0.600L

mol = 0.075 mol NaOH

In base on the reaction, it’s needed 1 mol of NaOH to neutralize 1 mole of HBr, so to neutralize 0.0625 moles of HBr its needed 0.0625 mol of NaOH:

0.075 mol NaOH – 0.0625 mol NaOH = 00125 NaOH

These are the moles free in the solution, and we going to use them to calculate the pH:

pOH = -log [ OH]

pOH = - log [ 0.0125 ] = 1.90

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As it is mentioned that 1 cubic centimeter contains 11.3 grams of lead.

So, in 2 cubic centimeter there will be 2 \times 11.3 g = 22.6 g of lead atoms.

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