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Tanya [424]
3 years ago
8

If 0.500 mol of acetylene is allowed to completely react with oxygen, what is the final yield of CO2 in moles?

Chemistry
1 answer:
Salsk061 [2.6K]3 years ago
4 0

Answer:

1.00 moles of CO2 is the final yield.

Explanation:

Based on the reaction:

2C2H2(g)+ 5O2(g) → 4CO2(g) + 2H2O(g)

<em>When 2 moles of acetylene (C2H2) completely reacts with oxygen, 4 moles of CO2 are produced.</em>

To solve this question we must use the chemical equation knowing: 2 moles C2H2 = 4 mol CO2

When 0.500 moles of acetylene react:

0.500 moles C2H2 * (4mol CO2 / 2mol C2H2) =

<h3>1.00 moles of CO2 is the final yield</h3>

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In this problem, the weak electrolyte is HNO₂(aq) and the salt is KNO₂(aq). In equation, the buffer solution is 0.55M HNO₂ ⇄ H⁺ + 0.75M KNO₂⁻ . The potassium ion is a spectator ion and does not enter into determination of the pH of the solution. The object is to determine the hydronium ion concentration (H⁺) and apply to the expression pH = -log[H⁺].

Solution using the I.C.E. table:

              HNO₂ ⇄    H⁺   +   KNO₂⁻

C(i)        0.55M       0M      0.75M

ΔC            -x            +x          +x

C(eq)  0.55M - x       x     0.75M + x    b/c [HNO₂] / Ka > 100, the x can be                                    

                                                             dropped giving ...

           ≅0.55M        x       ≅0.75M        

Ka = [H⁺][NO₂⁻]/[HNO₂] => [H⁺] = Ka · [HNO₂]/[NO₂⁻]

=> [H⁺] = 6.80x010⁻⁴(0.55) / (0.75) = 4.99 x 10⁻⁴M

pH = -log[H⁺] = -log(4.99 x 10⁻⁴) -(-3.3) = 3.3

Solution using the Henderson-Hasselbalch Equation:

pH = pKa + log[Base]/[Acid] = -log(Ka) + log[Base]/[Acid]

= -log(6.8 x 10⁻⁴) + log[(0.75M)/(0.55M)]

= -(-3.17) + 0.14 = 3.17 + 0.14 = 3.31 ≅ 3.3

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