There is a rule in naming polyatomic anions containing oxygen. Those names ending in –ate are given to the most common oxyanion of an element. While those names ending in –ite are for those that contains fewer O atom for the same charge. Since P $PO_{3} ^{3-}$ has fewer O atoms, its name ends in –ite. Thus, P $PO_{3} ^{3-}$ is phosphite while P $PO_{4} ^{3-}$ is phosphate.

4 0

3 years ago

A 100.0-mL sample of 1.00 M NaOH is mixed with 50.0 mL of 1.00 M H2SO4 in a large Styrofoam coffee cup calorimeter fitted with a

worty [1.4K]

Answer:

THE ENTHALPY CHANGE IN KJ/MOLE IS +114 KJ/MOLE.

Explanation:

Heat = mass * specific heat capacity * temperature rise

Total volume = 100 + 50 = 150 mL

Total mass = density * volume

Total mass = 1 * 150 mL = 150 g

So therefore, the heat evolved during the reaction is:

Heat = 150 * 4.18 * ( 31.4 - 22.3)

Heat = 150 * 4.18 * 9.1

Heat = 5705.7 J

Equation for the reaction:

2 NaOH(aq) + H2SO4(aq) → Na2SO4(aq) + 2 H2O(l)

From the equation, 2 moles of NaOH reacts with 1 mole of H2SO4 to produce 1 mole of Na2SO4 and 2 moles of water

50 mL of 1 M of H2SO4 contains

50 * 1 / 1000 mole of acid

= 0.05 mole of acid

The production of 1 mole of water evolved 5705.7 J of heat and hence the enthalpy changein kJ per mole will be:

0.05 mole of H2SO4 produces 5705.7 J of heat

1 mole of H2SO4 will produce 5705.7 / 0.05 J

= 114,114 J / mole

In kj/mole = 114 kJ/mole.

Hence, the enthalpy change of the reaction in kJ /mole is +114 kJ/mole.

5 0

3 years ago