Phosgene on reacting with <span>phenylmagnesium bromide generates
benzoyl chloride.
Since, </span>phenylmagnesium bromide is added in excess. It would further react with benzoyl chloride to form
benzophenone.
Benzophenone on further reacting with phenylmagnesium bromide, and aqueous treatment, gives
triphenylmethanol.
Entire reaction pathways is shown below:
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Resonance, leaving group, carbonyl carbon delta+, and steric effect is the most crucial variables that affect the relative reactivity of a functional group containing a carbonyl in an addition or substitution process.
Discussion:
1. Carbonyl Carbon Delta+: The carbonyl group becomes more electrophilic and accelerates nucleophilic assault when the carbonyl carbon delta+ is bigger.
2. Resonance: When the carbonyl is transformed into the tetrahedral adduct, it may be lost. Loss of resonance increases the energy of the transition state for this nucleophilic assault because resonance has the function of stabilizing. Therefore, a carbonyl functional group's resistance to nucleophilic attack increases as resonance in the group increases in importance.
3. Leaving group: Tetrahedral adduct fragmentation is encouraged by a better LG.
4. Steric effects: The nucleophilic attack on carbonyl carbon is delayed when sterically impeded.
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Answer:
Solubility, Volatility, Viscosity and Surface Tension.
Answer:
Whether something is a molecule or not depends on the type of bond that is formed when its atoms join together. In general, electrons can be shared between atoms (a molecular bond) or electrons can be completely removed from one atom and given to another (an ionic bond). Molecules have molecular bonds.