The middle nitrogen has two sigma bonds and one pi bond. You know that one p orbital is used in the double bond and two sp2 orbitals are involved in the sigma bond. This leaves one sp2 orbital for the lone pair to occupy.
Usually in this context you would be referring to the boiling and freezing point of a NaCl <em>solution</em> (saltwater) compared to pure H_{2}O. Sematics would be different for NaCl compound itself, you would say melting and boiling point for a solid substance- and the temperatures would be very, very radical (high).
The boiling point of pure water is 100 degrees C (212 F), and the freezing/melting point is below 0 degrees C (32 F). For a salt water solution, the boiling point is raised and the melting point is lowered. This means that water will stay liquid for an increased range of temperature. Depending on the amount of NaCl solute in the water, the boiling and melting points may change a few degrees.
: A chemical process of decomposition involving the splitting of a bond by the addition of water.
