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Explanation:
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Answer:
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Explanation:
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Answer is: ph value of pyridine solution is 9.1.
Chemical
reaction: C₅H₅N +
H₂O → C₅H₅NH⁺ + OH⁻.<span>
c(pyridine - C</span>₅H₅N)
= 0.115M.<span>
Kb(C</span>₅H₅N)
= 1.4·10⁻⁹.
[C₅H₅NH⁺] = [OH⁻] = x; equilibrium concentration.<span>
[</span>C₅H₅N] =
0.115 M - x.
Kb = [C₅H₅NH⁺] · [OH⁻] / [C₅H₅N].
1.4·10⁻⁹ = x² / (0.115 M -x)
Solve quadratic equation: x = [OH⁻] = 0.0000127 M.<span>
pOH = -log(0.0000127 M) = 4.9</span>
<span>pH = 14 - 4.9 = 9.1.</span>
So half life is the time taken for a sample to decay to half its original mass, its a constant and applies to any original mass, it could be 5g or 1kg, it will take the same amount of time for the original mass to half. In this case the half life is 3 days.
After 3 days the sample will be at half its original mass, now 50g.
Now we can treat the 50g as if its a new sample. After another 3 days (6 days in total) there will be half of 50g left, = 25g.