According to law of conservation of mass, mass can be neither be created nor be destroyed. The mass on reactant side must be equal to the mass on product side. Thus the atoms of each element on both side of the reaction must be same.
The balanced chemical reaction is:
Here 3 moles of Zn combine with 2 moles of to give 1 mole of and 3 moles of . Thus the mole ratio of Zn to ZnO is 3: 3.
It should be for the total solution of 93 plus 20 grams which is 113 grams so 93 divided by 113 grams comes to 82.3% sodium sulfate and this can be checked by multiplying 113 grams by 0.823 which results in 93 grams of sodium sulphate.