Three complete orders on each side of the m=0 order can be produced in addition to the m = 0 order.
The ruling separation is
d=1 / (470mm −1) = 2.1×10⁻³ mm
Diffraction lines occur at angles θ such that dsinθ=mλ, where λ is the wavelength and m is an integer.
Notice that for a given order, the line associated with a long wavelength is produced at a greater angle than the line associated with a shorter wavelength.
We take λ to be the longest wavelength in the visible spectrum (538nm) and find the greatest integer value of m such that θ is less than 90°.
That is, find the greatest integer value of m for which mλ<d.
since d / λ = 538×10⁻⁹m / 2.1×10 −6 m ≈ 3
that value is m=3.
There are three complete orders on each side of the m=0 order.
The second and third orders overlap.
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Answer:
See explanation and picture below
Explanation:
First, in the case of methyloxirane (Also known as propilene oxide) the mechanism that is taking place there is something similar to a Sn2 mechanism. Although a Sn2 mechanism is a bimolecular substitution taking place in only step, the mechanism followed here is pretty similar after the first step.
In both cases, the H atom of the HBr goes to the oxygen in the molecule. You'll have a OH⁺ in both. However, in the case of methyloxirane the next step is a Sn2 mechanism step, the bromide ion will go to the less substitued carbon, because the methyl group is exerting a steric hindrance. Not a big one but it has a little effect there, that's why the bromide will rather go to the carbon with more hydrogens. and the final product is formed.
In the case of phenyloxirane, once the OH⁺ is formed, the next step is a Sn1 mechanism. In this case, the bond C - OH⁺ is opened on the side of the phenyl to stabilize the OH. This is because that carbon is more stable than the carbon with no phenyl. (A 3° carbon is more stable than a 2° carbon). Therefore, when this bond opens, the bromide will go there in the next step, and the final product is formed. See picture below for mechanism and products.
%C= 12/12 + 2·16=0,273=27,3%.