The reaction mechanism for an alpha,beta-unsaturated ketone to react with basic peroxide to form an epoxide is shown below with a general ketone. The basic hydroxide is used to deprotonate the peroxide molecule to create a strong HOO- nucleophile. The peroxide then attacks the beta-carbon of the alkene and this pushes the electrons up to the oxygen of the carbonyl. This is the first intermediate that is formed during this reaction.
After the intermediate is formed, the lone pair from the oxygen pushes back down to form the carbonyl once more and this breaks a carbon-carbon bond which attacks the oxygen of the peroxy group, ultimately substituting an -OH group and forming the final epoxide ketone product.
Answer:
the properties of three undiscovered elements is the correct answer.
Explanation:
After he completed his work Mendeleev predicted the properties of the undiscovered elements.
In the year 1871, Dmitri Mendeleev predicted the detailed existence and the properties of the three elements that are undiscovered and he gained tremendous fame.
He left the gap in the table to put the elements which are not identified at that time and by glancing at the physical and chemical properties of an element next to the gap, Mendeleev could predict the properties of the not discovered elements.
Answer: Kinetic Energy is already moving and is not at rest. Potential Energy is purely based on the position of the object and also the condition of the object.
Explanation: hope this helps
Answer:
Explanation:
As per the law of conservation of mass all the mass of carbon present in the hydrocarbon weighing 112 g is present in the 328.5 g of carbon dioxide produced when the hydrocarbon was burned in air.
<u>1) Calculate the mass of carbon in 328.5 g of carbon dioxide</u>:
- Chemical formula of carbon dioxide: CO₂
- Molar mass of CO₂: 12.011 g/mol + 2 × 15.999 g/mol = 44.009 g/mol
x / 328.5 g CO₂ = 12.011 g C / 44.009 g/mol ⇒ x = 86.65 g C
<u>2) Calculate the percent mass of carbon:</u>
- % = (mass of carbon / mass of carbon dioxide) × 100 =
= (89.65 / 112) × 100 = 80.04%
Round to three signifcant figures: 80.0%.
