<u>Given:</u>
Change in internal energy = ΔU = -5084.1 kJ
Change in enthalpy = ΔH = -5074.3 kJ
<u>To determine:</u>
The work done, W
<u>Explanation:</u>
Based on the first law of thermodynamics,
ΔH = ΔU + PΔV
the work done by a gas is given as:
W = -PΔV
Therefore:
ΔH = ΔU - W
W = ΔU-ΔH = -5084.1 -(-5074.3) = -9.8 kJ
Ans: Work done is -9.8 kJ
NaOH reacts with CH3COOH in 1:1 molar ratio to produce CH3COONa
NaOH + CH3COOH → CH3COONa + H2O
Mol CH3COOH in 52.0mL of 0.35M solution = 52.0/1000*0.35 = 0.0182 mol CH3COOH
Mol NaOH in 19.0mL of 0.40M solution = 19.0/1000*0.40 = 0.0076 mol NaOH
These will react to produce 0.0076 mol CH3COONa and there will be 0.0182 - 0.0076 = 0.0106 mol CH3COOH remaining in solution unreacted . Total volume of solution = 52.0+19.0 = 71mL or 0.071L
Molarity of CH3COOH = 0.0106/0.071 = 0.1493M
CH3COONa = 0.0076 / 0.071 = 0.1070M
pKa acetic acid = - log Ka = -log 1.8*10^-5 = 4.74.
pH using Henderson - Hasselbalch equation:
pH = pKa + log ([salt]/[acid])
pH = 4.74 + log ( 0.1070/0.1493)
pH = 4.74 + log 0.717
pH = 4.74 + (-0.14)
pH = 4.60.
The chemical reaction would be as follows:
<span>2Na + S → Na2S
We are given the amount of the reactants to be used in the reaction. We use these to calculate the amount of product. We do as follows:
45.3 g Na ( 1 mol / 22.99 g ) = 1.97 mol Na
105 g S ( 1 mol / 32.06 g ) = 3.28 mol S
The limiting reactant would be Na. We calculate as follows:
1.97 mol Na ( 1 mol Na2S / 2 mol Na ) (78.04 g / mol ) = 76.87 g Na2S produced</span>
1. electrostatic interactions
<span>3. van de waals interactions </span>
<span>4. hydrogen bonding </span>