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Archy [21]
2 years ago
13

Explain how lone pairs of electrons influence the shape of a molecule.

Chemistry
1 answer:
Ronch [10]2 years ago
3 0

Explanation:

the lone pairs will be negatively charged. these have a repulsion effect on other negatively charged electrons in the shells of atoms. picture a water molecule: the lone electron pair on the top of the oxygen will have a repulsion force on the 2 hydrogen atom's orbiting electrons to cause a bent molecular geometry.

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Calculate the initial rate for the formation of c at 25 ∘c, if [a]=0.50m and [b]=0.075m
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The rate of formation of a product depends on the the concentrations of the reactants in a variable way.

If two products, call them A and B react together to form product C, a general equation for the formation of C has the form:

rate = k*[A]^m * [B]^n

Where the symbol [ ] is the concentration of each compound.

Then, plus the concentrations of compounds A and B you need k, m and n.

Normally you run controled trials in lab which permit to calculate k, m and n .

Here the data obtained in the lab are:

<span>Trial      [A]      [B]         Rate </span><span>
<span>            (M)     (M)          (M/s) </span>
<span>1         0.50    0.010      3.0×10−3 </span>
<span>2         0.50    0.020       6.0×10−3 </span>
<span>3         1.00 0  .010       1.2×10−2</span></span>


Given that for trials 1 and 2 [A] is the same you can use those values to find n, in this way

rate 1 = 3.0 * 10^ -3 = k [A1]^m * [B1]^n

rate 2 = 6.0*10^-3 = k [A2]^m * [B2]^n

divide rate / rate 1 => 2 = [B1]^n / [B2]^n

[B1] = 0.010 and [B2] = 0.020 =>

6.0 / 3.0  =( 0.020 / 0.010)^n =>

2 = 2^n => n = 1

 
Given that for data 1 and 3 [B] is the same, you use those data to find m

rate 3 / rate 1 = 12 / 3.0   = (1.0)^m / (0.5)^m =>

4 = 2^m => m = 2

Now use any of the data to find k

With the first trial: rate = 3*10^-3 m/s = k (0.5)^2 * (0.1) =>

k = 3.0*10^-3 m/s / 0.025 m^3 = 0.12 m^-2 s^-1

Now that you have k, m and n you can use the formula of the rate with the concentrations given

rate = k[A]^2*[B] = 0.12 m^-2 s^-1 * (0.50m)^2 * (0.075m) = 0.0045 m/s = 4.5*10^=3 m/s

Answer: 4.5 * 10^-3 m/s
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<h3>Answer:</h3>

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<h3>General Formulas and Concepts:</h3>

<u>Math</u>

<u>Pre-Algebra</u>

Order of Operations: BPEMDAS

  1. Brackets
  2. Parenthesis
  3. Exponents
  4. Multiplication
  5. Division
  6. Addition
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<u>Atomic Structure</u>

  • Avogadro's Number - 6.022 × 10²³ atoms, molecules, formula units, etc.

<u>Stoichiometry</u>

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<h3>Explanation:</h3>

<u>Step 1: Define</u>

1.2 × 10²⁴ molecules C₆H₁₂O₆ (glucose)

<u>Step 2: Identify Conversions</u>

Avogadro's Number

<u>Step 3: Convert</u>

  1. Set up:                               \displaystyle 1.2 \cdot 10^{24} \ molecules \ C_6H_{12}O_6(\frac{1 \ mol \ C_6H_{12}O_6}{6.022 \cdot 10^{23} \ molecules \ C_6H_{12}O_6})
  2. Divide:                                                                                                                      \displaystyle 1.99269 \ mol \ C_6H_{12}O_6

<u>Step 4: Check</u>

<em>Follow sig fig rules and round. We are given 2 sig figs.</em>

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