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stealth61 [152]
3 years ago
11

A 16.0 mL sample of a 1.04 M potassium sulfate solution is mixed with 14.3 mL of a 0.880 M barium nitrate solution and this prec

ipitation reaction occurs: K 2 S O 4 (aq)+Ba(N O 3 ) 2 (aq)→BaS O 4 (s)+2KN O 3 (aq) The solid BaS O 4 is collected, dried, and found to have a mass of 2.60 g . Determine the limiting reactant, the theoretical yield, and the percent yield.
Chemistry
1 answer:
stiks02 [169]3 years ago
5 0
Number of moles in the K2SO4 sample
= (16/1000)*1.04= 0.01664 mol

Number of moles in the Ba(NO3)2 sample
= (14.3/1000*0.880)= 0.01258 mol

Since the reaction is a 1:1 ratio between the two reactants, the limiting reagent is the one containing a smaller number of moles, namely Ba(NO3)2.

The molecular mass of BaSO4 is 137.3+(32.06+4*16.00)=233.4
Therefore the theoretical yield of Barium Sulphate is
233.4*0.01258=2.937 g
Actual yield = 2.60 g (given)
Therefore the percentage yield = 2.60/2.937=88.54%

Answer: 
1. the limiting reagent is Barium Nitrate (Ba(NO3)2)
2. the theoretical yield is 2.94 g
3. the percentage yield is 88.5%

I apologize for the mistake previous to this update.

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An unknown compound with a molar mass of 223.94 g/mol consists of 32.18% c, 4.50% h, and 63.32% cl. find the molecular formula f
Dima020 [189]

The actual number of atoms of each element present in the molecule of the compound is represented by the formula known as molecular formula.

Molar mass of the unknown compound = 223.94 g/mol (given)

Mass of each element present in the unknown compound is determined as:

  • Mass of carbon, C:

\frac{32.18}{100}\times 223.94 = 72.06 g

  • Mass of hydrogen, H:

\frac{4.5}{100}\times 223.94 = 10.08 g

  • Mass of chlorine, Cl:

\frac{63.32}{100}\times 223.94 = 141.79 g

Now, the number of each element in the unknown compound is determined by the formula:

number of moles = \frac{given mass}{molar mass}

  • Number of moles of C:

number of moles = \frac{72.06}{12} = 6.005 mole\simeq 6 mole

  • Number of moles of H:

number of moles = \frac{10.08}{1} = 10.08 mole\simeq 10 mole

  • Number of moles of Cl

number of moles = \frac{141.79}{35.5} = 3.99 mole\simeq 4 mole

Dividing each mole with the smallest number of mole, to determine the empirical formula:

C_{\frac{6}{4}}H_{\frac{10}{4}}Cl_{\frac{10}{4}}

C_{1.5}H_{2.5}Cl_{1}

Multiplying with 2 to convert the numbers in formula into a whole number:

So, the empirical formula is C_{3}H_{5}Cl_{2}.

Empirical mass = 12\times 3+1\times 5+2\times 35.5 = 112 g/mol

In order to determine the molecular formula:

n = \frac{molar mass}{empirical mass}

n = \frac{223.94}{112} = 1.99 \simeq 2

So, the molecular formula is:

2\times C_{3}H_{5}Cl_{2} =  C_{6}H_{10}Cl_{4}

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