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My name is Ann [436]
2 years ago
8

Hãy tìm công thức hóa học của những oxit có thành phần khối lượng như sau S:50%; C:42,8%; Mn:49,6%; Pb:86,6%

Chemistry
1 answer:
Novosadov [1.4K]2 years ago
3 0

Answer:

Find the chemical formulas of oxides that contain the following composition:

S:50%; C:42,8%; Mn:49,6%; Pb:86,6%

Explanation:

In the given oxide of sulphur,

50%S is present that means remaining 50% is O.

Divide the % with atomic mass:

S                                     O

50/32= 1.5625            50/16=3.125

divide with smallest ratio:

1.5625/1.5625=1              3.125/1.5625=2

Hence, the formula of oxide is SO_2.

Similarly:

Carbon is 42.8% means the reamining % will be O that is 57.2%.

C                                                    O

42.8/12=3.575                         57.2/16=3.575

Divide with smallest ratio:

3.575/3.575=1                            3.575/3.575=1

Hence, the formula of oxide is CO.

Mn is 49.6% means the remining is % is O that is 50.4%.

First divide with atmic mass of respective element, then get the smallest ratio.

That gives the mole ratio of each constituent atom.

Mn                                 O

49.6/55.0=0.90            50.4/16=3.15

0.90/0.90=1                   3.15/0.90=3.5

Multiply with two

2                                        7

Hence, the formula becomes:

Mn_2O_7

Pb is 86.6% means ---remaining 13.4% is O.

Pb                                               O

86.6/207 = 0.418 mol                13.4/16=0.85

0.418/0.418=1                               0.85/0.418=2.0

Hence, the formula is:PbO_2  

   

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We have the masses of two reactants, so this is a<em> limiting reactant problem.  </em>

We know that we will need a balanced equation with masses, moles, and molar masses of the compounds involved.  

<em>Step 1</em>. <em>Gather all the information</em> in one place with molar masses above the formulas and masses below them.  

M_r:        52.00   80.91       291.71

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Mass/g:  15.00    15.00  

<em>Step 2</em>. Calculate the <em>moles of each reactant</em>  

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Moles of HBr = 15.00 × 1/80.91

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<em>Step 3</em>. Identify the<em> limiting reactant</em>  

Calculate the moles of CrCl₃ we can obtain from each reactant.  

<em>From Cr</em>:

The molar ratio of CrBr₃:Cr is 2 mol CrBr₃:2 mol Cr

Moles of CrBr₃ = 0.2885 × 2/2

Moles of CrBr₃ = 0.2885 mol CrCl₃

<em>From HBr: </em>

The molar ratio of CrBr₃:HBr is 2 mol CrBr₃:6 mol HBr.

Moles of CrBr₃ = 0.1854 × 2/6

Moles of CrBr₃ = 0.061 80 mol CrBr₃

The limiting reactant is HBr because it gives the smaller amount of CrBr₃.

<em>Step 4</em>. Calculate the <em>theoretical yields</em> of CrBr₃ and H₂.

Theoretical yield of CrBr₃ = 0.061 80 × 291.71/1

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<em>Step 5</em>. Calculate the <em>volume of H₂</em> at STP

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The molar volume of a gas at STP is 22.71 L.

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       % yield = 15.35/18.03 × 100

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