Answer:
E = 1.602v
Explanation:
Use the Nernst Equation => E(non-std) = E⁰(std) – (0.0592/n)logQc …
Zn⁰(s) => Zn⁺²(aq) + 2 eˉ
2Ag⁺(aq) + 2eˉ=> 2Ag⁰(s)
_____________________________
Zn⁰(s) + 2Ag⁺(aq) => Zn⁺²(aq) + 2Ag(s)
Given E⁰ = 1.562v
Qc = [Zn⁺²(aq)]/[Ag⁺]² = (1 x 10ˉ³)/(0.150)² = 0.044
E = E⁰ -(0.0592/n)logQc = 1.562v – (0.0592/2)log(0.044) = 1.602v
Answer : The moles of
are, 2.125 mole.
Explanation : Given,
Molarity of
= 8.500 M
Volume of solution = 250 mL = 0.250 L (1 L = 1000 mL)
Molarity : It is defined as the number of moles of solute present in one liter of volume of solution.
Formula used :

Now put all the given values in this formula, we get:


Therefore, the moles of
are, 2.125 mole.
<h2>Heptene formed is -</h2><h2>

</h2>
Explanation:
The two possibilities when the peroxide is not present
+ HBr →
In presence peroxide,
≡
+ HBr →
- When peroxides are present in the reaction mixture, hydrogen bromide adds to the triple bond of heptane with regioselectivity.
- This reaction is opposite to that of Markovnikov's rule which says that when asymmetrical alkene reacts with a protic acid HX, then the hydrogen of an acid is attached to the carbon with more in number of hydrogen substituents, and the halide (X) group is attached to the carbon with more in number of substituents of alkyl.
- One mole of HBr adds to one mole of 1-heptane.
- The structure of heptene formed is -

Answer:
Reagent O₂ will be consumed first.
Explanation:
The balanced reaction between O₂ and C₄H₁₀ is:
2 C₄H₁₀ + 13 O₂ → 8 CO₂ + 10 H₂O
Then, by reaction stoichiometry, the following amounts of reactants and products participate in the reaction:
- C₄H₁₀: 2 moles
- O₂: 13 moles
- CO₂: 8 moles
- H₂O: 10 moles
Being:
- C: 12 g/mole
- H: 1 g/mole
- O: 16 g/mole
The molar mass of the compounds that participate in the reaction is:
- C₄H₁₀: 4*12 g/mole + 10*1 g/mole= 58 g/mole
- O₂: 2*16 g/mole= 32 g/mole
- CO₂: 12 g/mole + 2*16 g/mole= 44 g/mole
- H₂O: 2*1 g/mole + 16 g/mole= 18 g/mole
Then, by reaction stoichiometry, the following mass quantities of reactants and products participate in the reaction:
- C₄H₁₀: 2 moles* 58 g/mole= 116 g
- O₂: 13 moles* 32 g/mole= 416 g
- CO₂: 8 moles* 44 g/mole= 352 g
- H₂O: 10 moles* 18 g/mole= 180 g
If 78.1 g of O₂ react, it is possible to apply the following rule of three: if by stoichiometry 416 g of O₂ react with 116 g of C₄H₁₀, 62.4 g of C₄H₁₀ with how much mass of O₂ do they react?

mass of O₂= 223.78 grams
But 21.78 grams of O₂ are not available, 78.1 grams are available. Since you have less mass than you need to react with 62.4 g of C₄H₁₀, <u><em>reagent O₂ will be consumed first.</em></u>