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WINSTONCH [101]
3 years ago
6

Chlorine and potassium atoms form ionic bonds, carbon atoms form non-polar covalent bonds with nitrogen atoms, and oxygen forms

polar covalent bonds with phosphorus. Explain why these bonds are the types they are.
Chemistry
1 answer:
Ray Of Light [21]3 years ago
5 0

Explanation:

A covalent bond is formed when an element shares its valence electron with another element. This bond is formed between two non metals.

An ionic bond is formed when an element completely transfers its valence electron to another element. The element which donates the electron is known as electropositive element and the element which accepts the electrons is known as electronegative element. This bond is formed between a metal and an non-metal.

Chlorine and potassium atoms form ionic bonds: Ionic bond is formed when there is complete transfer of electron from a highly electropositive metal to a highly electronegative non metal.  Electronegativity difference = electronegativity of chlorine - electronegativity of potassium = 3-0.8 = 2.2

Carbon atoms form non-polar covalent bonds with nitrogen atoms : Non-polar covalent bond is defined as the bond which is formed when there is no difference of electronegativities between the atoms.  Electronegativity difference  = electronegativity of nitrogen  - electronegativity of carbon= 3.0-2.5 = 0.5

Oxygen forms polar covalent bonds with phosphorus: A polar covalent bond is defined as the bond which is formed when there is a difference of electronegativities between the atoms.  Electronegativity difference = electronegativity of oxygen - electronegativity of phosphorous = 3.5- 2.19 = 1.31

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Find the enthalpy of neutralization of HCl and NaOH. 137 cm3 of 2.6 mol dm-3 hydrochloric acid was neutralized by 137 cm3 of 2.6
liraira [26]

Answer : The correct option is, (D) 89.39 KJ/mole

Explanation :

First we have to calculate the moles of HCl and NaOH.

\text{Moles of HCl}=\text{Concentration of HCl}\times \text{Volume of solution}=2.6mole/L\times 0.137L=0.3562mole

\text{Moles of NaOH}=\text{Concentration of NaOH}\times \text{Volume of solution}=2.6mole/L\times 0.137L=0.3562mole

The balanced chemical reaction will be,

HCl+NaOH\rightarrow NaCl+H_2O

From the balanced reaction we conclude that,

As, 1 mole of HCl neutralizes by 1 mole of NaOH

So, 0.3562 mole of HCl neutralizes by 0.3562 mole of NaOH

Thus, the number of neutralized moles = 0.3562 mole

Now we have to calculate the mass of water.

As we know that the density of water is 1 g/ml. So, the mass of water will be:

The volume of water = 137ml+137ml=274ml

\text{Mass of water}=\text{Density of water}\times \text{Volume of water}=1g/ml\times 274ml=274g

Now we have to calculate the heat absorbed during the reaction.

q=m\times c\times (T_{final}-T_{initial})

where,

q = heat absorbed = ?

c = specific heat of water = 4.18J/g^oC

m = mass of water = 274 g

T_{final} = final temperature of water = 325.8 K

T_{initial} = initial temperature of metal = 298 K

Now put all the given values in the above formula, we get:

q=274g\times 4.18J/g^oC\times (325.8-298)K

q=31839.896J=31.84KJ

Thus, the heat released during the neutralization = -31.84 KJ

Now we have to calculate the enthalpy of neutralization.

\Delta H=\frac{q}{n}

where,

\Delta H = enthalpy of neutralization = ?

q = heat released = -31.84 KJ

n = number of moles used in neutralization = 0.3562 mole

\Delta H=\frac{-31.84KJ}{0.3562mole}=-89.39KJ/mole

The negative sign indicate the heat released during the reaction.

Therefore, the enthalpy of neutralization is, 89.39 KJ/mole

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If 1.50 L of 0.780 mol/L sodium sulfide is mixed with 1.00 L of a 3.31 mol/L lead(II) nitrate solution, what mass of precipitate
NARA [144]

Answer:

336.1 g of PbS precipitate

Explanation:

The equation of the reaction is given as;

Na2S(aq) + Pb(NO3)2(aq) ----> 2NaNO3(aq) + PbS(s)

Ionically;

Pb^2+(aq) + S^2-(aq) -----> PbS(s)

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Number of moles of sodium sulphide= 0.780 × 1.5 = 1.17 moles

Number of moles of lead II nitrate= concentration of lead II nitrate × volume of lead II nitrate

Number of moles of lead II nitrate= 3.31× 1.00= 3.31 moles

Then we determine the limiting reactant. The limiting reactant yields the least amount of product.

Since 1 moles of sodium sulphide yields 1 mole of lead II sulphide

1.17 moles of sodium sulphide also yields 1.17 moles of lead II sulphide

Hence sodium sulphide is the limiting reactant.

Thus mass of precipitate formed= amount of lead II sulphide × molar mass of sodium sulphide

Molar mass of lead II sulphide= 287.26 g/mol

Mass of lead II sulphide = 1.17 moles × 287.26 g/mol

Mass of lead II sulphide= 336.1 g of PbS precipitate

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