Answer:
A and D are true , while B and F statements are false.
Explanation:
A) True. Since the standard gibbs free energy is
ΔG = ΔG⁰ + RT*ln Q
where Q= [P1]ᵃ.../([R1]ᵇ...) , representing the ratio of the product of concentration of chemical reaction products P and the product of concentration of chemical reaction reactants R
when the system reaches equilibrium ΔG=0 and Q=Keq
0 = ΔG⁰ + RT*ln Q → ΔG⁰ = (-RT*ln Keq)
therefore the first equation also can be expressed as
ΔG = RT*ln (Q/Keq)
thus the standard gibbs free energy can be determined using Keq
B) False. ΔG⁰ represents the change of free energy under standard conditions . Nevertheless , it will give us a clue about the ΔG around the standard conditions .For example if ΔG⁰>>0 then is likely that ΔG>0 ( from the first equation) if the temperature or concentration changes are not very distant from the standard conditions
C) False. From the equation presented
ΔG⁰ = (-RT*ln Keq)
ΔG⁰>0 if Keq<1 and ΔG⁰<0 if Keq>1
for example, for a reversible reaction ΔG⁰ will be <0 for forward or reverse reaction and the ΔG⁰ will be >0 for the other one ( reverse or forward reaction)
D) True. Standard conditions refer to
T= 298 K
pH= 7
P= 1 atm
C= 1 M for all reactants
Water = 55.6 M
Answer:
0.185M sulfuric acid
Explanation:
Based on the reaction:
H₂SO₄ + 2KOH → K₂SO₄ + 2H₂O
<em>1 mole of sulfuric acid reacts with 2 moles of KOH</em>
Initial moles of H₂SO₄ and KOH are:
H₂SO₄: 0.750L ₓ (0.470mol / L) = <em>0.3525 moles of H₂SO₄</em>
KOH: 0.700L ₓ (0.240mol / L) = <em>0.168 moles of KOH</em>
The moles of sulfuric acis that react with KOH are:
0.168mol KOH ₓ (1 mole H₂SO₄ / 2 moles KOH) = 0.0840 moles of sulfuric acid.
Thus, moles that remain are:
0.3525moles - 0.0840 moles = <em>0.2685 moles of sulfuric acid remains</em>
As total volume is 0.700L + 0.750L = 1.450L, concentration is:
0.2685mol / 1.450L = <em>0.185M sulfuric acid</em>
Heat of vaporization of water will be required as water is already at it's boiling point thus heat required will be 540*10=5400 cal
Answer:
Increase pressure 3X => increase Temperature 3X
Explanation:
Gay-Lussac Law => T ∝ P => T =kP => Empirical Relationship => T₁/P₁ = T₂/P₂
=> T₂ = T₁P₂/P₁
Given P₂ = 3P₁ => T₂ = T₁(3P₁)/P₁ = 3T₁
Answer:
D.
Explanation:
I just got it right in the test :)
