Answer:
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Explanation:
我實際上不知道答案,我只是為了點數而這樣做,哈哈,祝你好運哈哈我實際上不知道答案,我只是為了點數而這樣做,哈哈,祝你好運哈哈我實際上不知道答案,我只是為了點數而這樣做,哈哈,祝你好運哈哈
Answer:
Reaction mechanism has been given below
Explanation:
- Propanoyl chloride contains an electrophilic carbonyl center to give nucleophilic acyl substitution reaction by removing Cl group with a strong nucleophile like methylmagnesium bromide.
- Two equivalent of methyl magnesium bromide react with cabonyl center followed by protonation of negatively charged oxygen atom gives 2-methyl-2-butanol.
- In the first step, nucleophilic acyl substituion occurs. In the second step, nucleophilic addition occurs. In the third step, protonation occurs.
- Reaction mechanism has been shown below.
Answer:
T f = (Normal freezing point of benzene - Molality of the solution × freezing point depression per molal of benzene) = 5.5 ° C - .625 m × 5.12° C = 2.30° C.
T f = 2.30° C.
T b = (Normal boiling point of benzene - Molality of the solution × boiling point elevation per molal of benzene) = 80.1 ° C. - .625 × 2.53° C = 81.68 ° C.
T b = 81.68 ° C.
Explanation:
The molality of the solution is .541 ÷ .865 = .625 m.
Ideally benzene freezes at 5.5 ° C and the depression of the freezing point is 5.12° C per molal.
At a molality of 0.625 the freezing point will be depressed by (molality of solution × freezing point depression per molal of benzene) or .625 × 5.12° C = 3.20° C. So the resulting freezing point will be (Ideal freezing point - freezing point depression) or T f =5.5 ° C. - 3.20 ° C. = 2.30° C.
Also ideally benzene boils at a temperature of 80.1° C and the elevation of the boiling point per molal is 2.53° C . So the boiling point of benzene will be elevated by (molality of solution × boiling point elevation per molal of benzene) .625 × 2.53° C = 1.58° C. So the boiling point of the current solution, T b, will be 80.1 ° C. + 1.58 ° C. = 81.68 ° C.