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Butoxors [25]
3 years ago
8

. KMnO4 oxidizes ethyl benzene to benzoic acid. If this reaction generally results in a 40 % experimental yield, how many grams

of ethyl benzene are required to obtain 244 g of benzoic acid
Chemistry
1 answer:
lyudmila [28]3 years ago
7 0

Answer:

530.835 g

Explanation:

First we convert 244 g of benzoic acid (C₇H₆O₂) to moles, using its molar mass:

  • 244 g benzoic acid ÷ 122.12 g/mol = 2.00 moles benzoic acid

Theoretically,<em> one mol of ethyl benzene would produce one mol of benzoic acid</em>. But the experimental yield tells us that one mol of ethyl benzene will produce only 0.4 moles of benzoic acid.

With the above information in mind we convert 2.00 moles of benzoic acid into moles of ethyl benzene:

  • 2.00 moles benzoic acid * \frac{1molEthylBenzene}{0.4molBenzoicAcid} = 5.00 moles ethyl benzene

Finally we <u>convert moles of ethyl benzene </u>(C₈H₁₀)<u> into grams</u>, using its <em>molar mass</em>:

  • 5.00 moles ethyl benzene * 106.167 g/mol = 530.835 g ethyl benzene
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At a particular temperature, Kp 0.25 for the reaction a. A ask containing only N2O4 at an initial pressure of 4.5 atm is allowed
Alex

Answer:

a.  pNO₂ = 1 atm    pN₂O₄ = 4 atm

b.  pNO₂ = 1 atm    pN₂O₄ = 4 atm

c. It does not matter.

Explanation:

From the information given in this question we know the equilibrium involved is

N₂O₄ (g) ⇄ 2 NO₂ (g)

with Kp  given by

Kp = p NO₂²/ p N₂O₄ = 0.25

We know that if we place 4.5 atm of N₂O₄ is placed in a flask, a quantity x is going to be consumed producing 2x atm of NO₂  and we can setup the following equation:

0.25 =  p NO₂²/ p N₂O₄ =  (2x)² / (4.5 - x)

0.25 x  (4.5 - x) = 4x²

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after solving this quadratic equation, we get two roots

x₁ = 0.5

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the second root is physically impossible, and the partial pressures for x₁ = 0.5  will be

pNO₂ = 2 x 0.5 atm = 1.0 atm

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Similarly for part b, we get the equilibrium equation

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0.25x = 81 - 36x + 4x²

the roots of this equation are:

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the second root give us the following partial pressures:

p N₂O₄ = (9 - 2x4) atm = 1 atm

p NO₂ = 4 atm

The partial pressures are the same, it does not matter from which direction an equilibrium position is reached since what is essential is that the partial pressures of the gasses N₂O₄ and  NO₂ obey the equilibrium equation.

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