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zubka84 [21]
3 years ago
15

Calculate the pH of the solution that results when 20 mL of 0.2M HCOOH is mixed with 25mL of 0.2M NaOH solution.(post-equivalenc

e point)​
Chemistry
1 answer:
Paul [167]3 years ago
3 0

The pH of the solution : 12

<h3>Further explanation</h3>

Reaction

HCOOH    +     NaOH   ⇒     HCOONa   +   H₂O

mol HCOOH =

\tt 20~ml\times 0.2~M=4~mlmol

mol NaOH =

\tt 25~ml\times 0.2~M=5~mlmol

Mol NaOH>mol HCOOH ⇒ at the end of the reaction there will be a strong base remains from mol NaOH, so that the pH is determined from [OH⁻]

ICE method :

HCOOH    +     NaOH   ⇒     HCOONa   +   H₂O

4                          5

4                          4                     4                   4

0                          1                      1                    1

Concentration of [OH⁻] from NaOH :

\tt \dfrac{1~mlmol}{20+25~ml}=0.02

pOH=-log[OH⁻]

pOH=-log 10⁻²=2

pH+pOH=14

pH=14-2=12

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