A body can be charged when another body is made to touch it such that charges are transferred from a charged body to an uncharged body. This is known as charging by contact.
A body can also be charged by induction. In this case, a charged body is only brought near an uncharged body without really touching the uncharged body. Charges are transferred without physical contact of the bodies.
PF3Br2 has a trigonal bypiramidal geometry. The three atoms of F will be arranged around the P atom in the same plane and each F-P-F bond will have an angle of 120 degrees. There will be only one Br atom above and beneath the P atom so the bond angle for Br-P-Br will be 180 degrees. Finally, the F−P−Br bond angle will be at 90 degrees.