1 carbon and 2 oxygen atoms CO2
In 0.190 mole of C6H14O, there is 0.190*6 (number of C in one molecule) = 1.140 mole of C atoms. The total number of C atoms = 1.14 * 6*

(atoms of C in one mole) = 6.84*

atoms.
For the equation to be balanced, the Atom's coefficient on the left side and the right side of the equation has to be equal
so, the answer would be :
Br2 + S2032- + 5H20 -- > BR2- + 2S02- + H+
Hope this helps