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torisob [31]
3 years ago
13

In each of the following indicate which reaction will occur faster. Explain your reasoning. (a) CH3CH2CH2CH2Br or CH3CH2CH2CH2I

with sodium cyanide in dimethyl sulfoxide (b) 1-Chloro-2-methylbutane or 1-chloropentane with sodium iodide in acetone (c) Hexyl chloride or cyclohexyl chloride with sodium azide in aqueous ethanol (d) Solvolysis of 1-bromo-2,2-dimethylpropane or tert-butyl bromide in ethanol (e) Solvolysis of isobutyl bromide or sec-butyl bromide in aqueous formic acid (f) Reaction of 1-chlorobutane with sodium acetate in acetic acid or with sodium methoxide in methanol (g) Reaction of 1-chlorobutane with sodium azide or sodium p-toluenesulfonate in aqueous ethanol
Chemistry
1 answer:
Elena L [17]3 years ago
5 0

Answer:

A. Butyliodide will react faster than butylbromide, this is because iodide is a better leaving group in substitution reaction than bromide. B. 1-chloropentane is more reactive than 1-chloro2methylbutane, this is because Alkyl groups at the carbon atom decrease the reaction rate of SN2 reaction. C. Chloro- hexanechloride is more reactive than hexyl chloride because determining the rate of reaction in SN1 reaction of formation of carbocation is more stable than the primary one. SN1 reaction is a secondary carbocation reaction. D. Terri-butylbromide is more reactive than 1-bromo 2,2 dimethylpropane, this is because Tertiary carbocation is stable compared to the primary, this is because the rate of determining step involved in SN1 reaction. E. Sec-butyl bromide is more reactive than isobutylbromide, this is because Sec-butyl bromide belong to the secondary all halide why the other belongs to primary class. F. The reaction is faster in sodium methoxide in methanol than sodium acetate in acetic acid, this is because 1-chlorobutane is a primary alklyl- chloride than and the strength of nuclephile determines the rate of reaction. G. when sodium azide mixed with ethanol is used, the reaction will be faster, because strong acid form weak conjuage base and also azide is a better nuclephile.

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Answer: it honestly depends.

Explanation:

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The rate constant for the reaction 3A equals 4b is 6.00×10 how long will it take the concentration of a to drop from 0.75 to 0.2
Lelu [443]

This question is incomplete, the complete question is;

The rate constant for the reaction 3A equals 4B is 6.00 × 10⁻³ L.mol⁻¹min⁻¹.

how long will it take the concentration of A to drop from 0.75 to 0.25M ?

from the unit of the rate constant we know it is a second reaction order

OPTIONS

a) 2.2×10^−3 min

b) 5.5×10^−3 min

c) 180 min

d) 440 min

e) 5.0×10^2 min

Answer:

it will take 440 min for the concentration of A to drop from 0.75 to 0.25M

Option d) 440 min is the correct answer

Explanation:

Given that;

Rate constant K =  6.00 × 10⁻³ L.mol⁻¹min⁻¹

3A → 4B

given that it is a second reaction order;

k = 1/t [ 1/A - 1/A₀]

kt = [ 1/A - 1/A₀]

t = [ 1/A - 1/A₀] / k

K is the rate constant(6.00 × 10⁻³)

A₀ is initial concentration( 0.75 )

A is final concentration(0.25)

t is time required = ?

so we substitute our values into the equation

t = [ (1/0.25) - (1/0.75)] / (6.00 × 10⁻³)

t = 2.6666 / (6.00 × 10⁻³)

t = 444.34 ≈ 440 min     {significant figures}

Therefore it will take 440 min for the concentration of A to drop from 0.75 to 0.25M

Option d) 440 min is the correct answer

6 0
3 years ago
The following thermochemical equation is for the reaction of Fe 3 O 4 (s) with hydrogen (g) to form iron and water vapor Fe 3 O
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Answer:

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Explanation:

Based in the reaction:

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<em>1 mole of Fe3O4 reacts with 4 moles of H₂, 151kJ are absorbed.</em>

63.4g of Fe₃O₄ (Molar mass: 231.533g/mol) are:

63.4g Fe₃O₄ × (1mol / 231.533g) = <em>0.274moles of Fe₃O₄</em>

These are the moles of Fe₃O₄ that react. As 1 mole of Fe₃O₄ in reaction absorb 151kJ, 0.274moles absorb:

0.274moles of Fe₃O₄ × (151kJ / 1 mole Fe₃O₄) =

<h3>41.3kJ of heat is absorbed</h3>

<em />

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There are two meanings to the word "Distal"

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Explanation:

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