Answer:

Explanation:
Hello,
In this case, for the given reaction at equilibrium:

We can write the law of mass action as:
![Keq=\frac{[CH_3OH]}{[CO][H_2]^2}](https://tex.z-dn.net/?f=Keq%3D%5Cfrac%7B%5BCH_3OH%5D%7D%7B%5BCO%5D%5BH_2%5D%5E2%7D)
That in terms of the change
due to the reaction extent we can write:
![Keq=\frac{x}{([CO]_0-x)([H_2]_0-2x)^2}](https://tex.z-dn.net/?f=Keq%3D%5Cfrac%7Bx%7D%7B%28%5BCO%5D_0-x%29%28%5BH_2%5D_0-2x%29%5E2%7D)
Nevertheless, for the carbon monoxide, we can directly compute
as shown below:
![[CO]_0=\frac{0.45mol}{1.00L}=0.45M\\](https://tex.z-dn.net/?f=%5BCO%5D_0%3D%5Cfrac%7B0.45mol%7D%7B1.00L%7D%3D0.45M%5C%5C)
![[H_2]_0=\frac{0.57mol}{1.00L}=0.57M\\](https://tex.z-dn.net/?f=%5BH_2%5D_0%3D%5Cfrac%7B0.57mol%7D%7B1.00L%7D%3D0.57M%5C%5C)
![[CO]_{eq}=\frac{0.28mol}{1.00L}=0.28M\\](https://tex.z-dn.net/?f=%5BCO%5D_%7Beq%7D%3D%5Cfrac%7B0.28mol%7D%7B1.00L%7D%3D0.28M%5C%5C)
![x=[CO]_0-[CO]_{eq}=0.45M-0.28M=0.17M](https://tex.z-dn.net/?f=x%3D%5BCO%5D_0-%5BCO%5D_%7Beq%7D%3D0.45M-0.28M%3D0.17M)
Finally, we can compute the equilibrium constant:

Best regards.
<u>Answer:</u> The tree was burned 16846.4 years ago to make the ancient charcoal
<u>Explanation:</u>
The equation used to calculate rate constant from given half life for first order kinetics:

where,
= half life of the reaction = 5715 years
Putting values in above equation, we get:

Rate law expression for first order kinetics is given by the equation:
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = 
t = time taken for decay process = ? yr
= initial amount of the sample = 100 grams
[A] = amount left after decay process = 13 grams
Putting values in above equation, we get:

Hence, the tree was burned 16846.4 years ago to make the ancient charcoal
Answer:
(a) rate = 4.82 x 10⁻³s⁻¹ [N2O5]
(b) rate = 1.16 x 10⁻⁴ M/s
(c) rate = 2.32 x 10⁻⁴ M/s
(d) rate = 5.80 x 10⁻⁵ M/s
Explanation:
We are told the rate law is first order in N₂O₅, and its rate constant is 4.82 x 10⁻³s⁻¹ . This means the rate is proportional to the molar concentration of N₂O₅, so
(a) rate = k [N2O5] = 4.82 x 10⁻³s⁻¹ x [N2O5]
(b) rate = 4.82×10⁻³s⁻¹ x 0.0240 M = 1.16 x 10⁻⁴ M/s
(c) Since the reaction is first order if the concentration of N₂O₅ is double the rate will double too: 2 x 1.16 x 10⁻⁴ M/s = 2.32 x 10⁻⁴ M/s
(d) Again since the reaction is halved to 0.0120 M, the rate will be halved to
1.16 x 10⁻⁴ M/s / 2 = 5.80 x 10⁻⁵ M/s
Explanation:
This is because gas particles are free to move as they are not held in place by strong molecular forces while particles in a solid are
7.5 is the answer. You have to move the decimal 2 places to the right.