A vessel of 356 cm3 capacity contains oxygen at a pressure of 760 mmHg and temperature of 15 oC. Assuming that the volume remain
1 answer:
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0.042 moles of Hydrogen evolved
<h3>Further explanation</h3>Given
I = 1.5 A
t = 1.5 hr = 5400 s
Required
Number of Hydrogen evolved
Solution
Electrolysis of water ⇒ decomposition reaction of water into Oxygen and Hydrogen gas.
Cathode(reduction-negative pole) : 2H₂O(l)+2e⁻ ⇒ H₂(g)+2OH⁻(aq)
Anode(oxidation-positive pole) : 2H₂O(l)⇒O₂(g)+4H⁻(aq)+4e⁻
Total reaction : 2H₂O(l)⇒2H₂(g)+O₂(g)
So at the cathode H₂ gas is produced
Faraday : 1 mole of electrons (e⁻) contains a charge of 96,500 C
Q = i.t
Q = 1.5 x 5400
Q = 8100 C
mol e⁻ = 8100 : 96500 = 0.084
From equation at cathode , mol ratio e⁻ : H₂ = 2 : 1, so mol H₂ = 0.042
Answer: The bond between boron and hydrogen in boron trihydride is covalent bond.
Explanation:
The type of bonding between the atoms forming a compound is determined by using the electronegativity difference between the atoms. According to the pauling's electronegativity rule:
- If
, then the bond is non-polar.
- If
, then the bond will be covalent.
- If
, then the bond will be ionic.
We are given:
Electronegativity for boron = 2.0
Electronegativity for hydrogen = 2.1
As, is less than 1.7 and not equal to 0. Hence, the bond between boron and hydrogen is covalent bond.