First we have to find Ka1 and Ka2
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =
![\frac{[H^+][HC2O4^-]}{[H2C2O4]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BH%5E%2B%5D%5BHC2O4%5E-%5D%7D%7B%5BH2C2O4%5D%7D%20)
= x² / 0.0356 - x
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6
Answer:
pH = 12.22
Explanation:
<em>... To make up 170mL of solution... The temperature is 25°C...</em>
<em />
The dissolution of Barium Hydroxide, Ba(OH)₂ occurs as follows:
Ba(OH)₂ ⇄ Ba²⁺(aq) + 2OH⁻(aq)
<em>Where 1 mole of barium hydroxide produce 2 moles of hydroxide ion.</em>
<em />
To solve this question we need to convert mass of the hydroxide to moles with its molar mass. Twice these moles are moles of hydroxide ion (Based on the chemical equation). With moles of OH⁻ and the volume we can find [OH⁻] and [H⁺] using Kw. As pH = -log[H⁺], we can solve this problem:
<em>Moles Ba(OH)₂ molar mass: 171.34g/mol</em>
0.240g * (1mol / 171.34g) = 1.4x10⁻³ moles * 2 =
2.80x10⁻³ moles of OH⁻
<em>Molarity [OH⁻] and [H⁺]</em>
2.80x10⁻³ moles of OH⁻ / 0.170L = 0.01648M
As Kw at 25°C is 1x10⁻¹⁴:
Kw = 1x10⁻¹⁴ = [OH⁻] [H⁺]
[H⁺] = Kw / [OH⁻] = 1x10⁻¹⁴/0.01648M = 6.068x10⁻¹³M
<em>pH:</em>
pH = -log [H⁺]
pH = -log [6.068x10⁻¹³M]
<h3>pH = 12.22</h3>
Answer:
0.85 mole of PBr3.
Explanation:
We'll begin by writing the balanced equation for the reaction. This is given below:
3Br2 + 2P —> 2PBr3
From the balanced equation above,
3 moles of Br2 reacted to produce 2 moles of PBr3.
Therefore, 1.27 moles of Br2 will react to produce = (1.27 x 2)/ 3 = 0.85 mole of PBr3.
Therefore, 0.85 mole of PBr3 is produced by the reaction.
Answer:
Q = 2640.96 J
Explanation:
Given data:
Mass of He gas = 10.7 g
Initial temperature = 22.1°C
Final temperature = 39.4°C
Heat absorbed = ?
Solution:
Specific heat capacity:
It is the amount of heat required to raise the temperature of one gram of substance by one degree. Specific heat capacity of He is 14.267 J/g.°C
Formula:
Q = m.c. ΔT
Q = amount of heat absorbed or released
m = mass of given substance
c = specific heat capacity of substance
ΔT = change in temperature
ΔT = 39.4°C - 22.1°C
ΔT = 17.3°C
Q = 10.7 g× 14.267 J/g.°C × 17.3°C
Q = 2640.96 J
Answer:
B.) If sodium carbonate is added to vinegar, the reaction will absorb heat.
Explanation:
A.) is incorrect because this is not testable. Rather, it is just an opinion that cannot be proven correct or incorrect.
B.) is correct because this statement is testable. Tests need to be run to determine the accuracy of the statement.
C.) is incorrect because this statement explains something that does not need to be tested. It is an example of a physical change when one tears a piece of paper.
D.) is incorrect because this is already a true statement. It is obvious that not all reactions absorb/release heat. While tests could be run to further prove this statement true, it is already considered accurate.
