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klemol [59]
3 years ago
13

What volume of a 2.0M NaOH(aq) is needed to completely neutralize 24 milliliters of 0.5M HCl(aq)?

Chemistry
1 answer:
borishaifa [10]3 years ago
8 0

Answer:

V_{base}=6.0mL

Explanation:

Hello there!

In this case, by considering that the reaction between sodium hydroxide and hydrochloric acid is in a 1:1 mole ratio of these two reactants, we are able to use the following equation relating the concentration and volume of each one:

M_{acid}V_{acid}=M_{base}V_{base}

In such a way, by solving for the volume of the base, we will obtain:

V_{base}=\frac{M_{acid}V_{acid}}{M_{base}} \\\\V_{base}=\frac{0.5M*24mL}{2.0M}\\\\V_{base}=6.0mL

Regards!

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The correct answer is B.

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The equilibrium constant in terms of pressure. Kp for the following process is 0.179 at 50 °C. It increases to 0.669 at 86 °C. C
Vikentia [17]

Answer:

a) ΔHvap=35.3395 kJ/mol

b) Tb=98.62 °C

Explanation:

Given the reaction:

C₇H₁₆ (l) ⇔ C₇H₁₆ (g)

Kp=P(C₇H₁₆) since the concentration ratio for a pure liquid is equal to 1.

When

T₁=50°C=323.15K ⇒P₁=0.179

T₂=86°C=359.15K ⇒P₂=0.669

The Clasius-Clapeyron equation is:

ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})

ln(\frac{0.669}{0.179}) =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{359.15K}-\frac{1}{323.15K})

1.3184 =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (-3.10186*10^{-4}K{^-1})

ΔHvap=35339.5 J/mol=35.3395 KJ/mol

Normal boiling point ⇒ P=1 atm

Hence, we find the normal boiling point where:

T₁=323.15K

P₁=0.179 atm

P₂=1 atm

ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})

ln(\frac{1atm}{0.179atm}) =-\frac{35339.5 J/mol}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{T_2}-\frac{1}{323.15K})

1.7203=-4250.34 (\frac{1}{T_2}-\frac{1}{323.15K})

T₂=371.77 K= 98.62 °C

5 0
3 years ago
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Answer:

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Explanation:

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2 years ago
How can you determine which bond in a structure is more polar without using an electronegativity table?
UkoKoshka [18]
To know this you pretty much do have to kind of memorize a few electronegativities. I don't recall ever getting a table of electronegativities on an exam.
From the structure, you have:

I remember the following electronegativities most because they are fairly patterned:
EN
H
=
2.1
EN
C
=
2.5
EN
N
=
3.0
EN
O
=
3.5
EN
F
=
4.0
EN
Cl
=
3.5
Notice how carbon through fluorine go in increments of
~
0.5
. I believe Pauling made it that way when he determined electronegativities in the '30s.
Δ
EN
C
−
Cl
=
1.0
Δ
EN
C
−
H
=
0.4
Δ
EN
C
−
C
=
0.0
Δ
EN
C
−
O
=
1.0
Δ
EN
O
−
H
=
1.4
So naturally, with the greatest electronegativity difference of
4.0
−
2.5
=
1.5
, the
C
−
F
bond is most polar, i.e. that bond's electron distribution is the most drawn towards the more electronegative compound as compared to the rest.
When the electron distribution is polarized and drawn towards a more electronegative atom, the less electronegative atom has to move inwards because its nucleus was previously favorably attracted to the electrons from the other atom.
That means generally, the greater the electronegativity difference between two atoms is, the shorter you can expect the bond to be, insofar as the electronegative atom is the same size as another comparable electronegative atom.
However, examining actual data, we would see that on average, in conditions without other bond polarizations occuring:
r
C
−
Cl
≈
177 pm
r
C
−
C
≈
154 pm
r
C
−
O
≈
143 pm
r
C
−
F
≈
135 pm
r
C
−
H
≈
109 pm
r
O
−
H
≈
96 pm
So it is not necessarily the least electronegativity difference that gives the longest bond.
Therefore, you cannot simply consider electronegativity. Examining the radii of the atoms, you should notice that chlorine is the biggest atom in the compound.
r
Cl
≈
79 pm
r
C
≈
70 pm
r
H
≈
53 pm
r
O
≈
60 pm
So assuming the answer is truly
C
−
C
, what would have to hold true is that:
The
C
−
F
bond polarization makes the carbon more electropositive (which is true).
The now more electropositive carbon wishes to attract bonding pairs from chlorine closer, thereby shortening the
C
−
Cl
bond, and potentially the
C
−
H
bond (which is probably true).
The shortening of the
C
−
Cl
bond is somehow enough to be shorter than the
C
−
C
bond (this is debatable).
5 0
3 years ago
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