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lara31 [8.8K]
3 years ago
15

The half-reaction at the cathode in an electrochemical cell is given below.

Chemistry
1 answer:
olga55 [171]3 years ago
7 0

Explanation:

a) Anode:  

Cathode :  

b)  

c) As  , the reaction is spontaneous.

d)  

Explanation:

a) Here Ni undergoes oxidation by loss of electrons, thus act as anode. Hydrogen undergoes reduction by gain of electrons and thus act as cathode.

Anode:  

Cathode :  

b) The representation is given by writing the anode on left hand side followed by its ion with its molar concentration. It is followed by a slat bridge. Then the cathodic ion with its molar concentration is written and then the cathode.

c)  

Where both  are standard reduction potentials.

= +ve, reaction is spontaneous

= -ve, reaction is non spontaneous

= 0, reaction is in equilibrium

Thus as  , the reaction is spontaneous.

d) The standard emf of a cell is related to Gibbs free energy by following relation:

= standard gibbs free energy

n= no of electrons gained or lost

F= faraday's constant

= standard emf

Thus value of Gibbs free energy is -48250 Joules.

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During the chemical reaction given below 21.71 grams of each reagent were allowed to react. Determine how many grams of the exce
swat32

Answer: 16.32 g of O_2 as excess reagent are left.

Explanation:

To calculate the moles :

\text{Moles of solute}=\frac{\text{given mass}}{\text{Molar Mass}}    

\text{Moles of} SO_2=\frac{21.71g}{64g/mol}=0.34mol

\text{Moles of} O_2=\frac{21.71g}{32g/mol}=0.68mol

2SO_2(g)+O_2(g)\rightarrow 2SO_3(g)  

According to stoichiometry :

2 moles of SO_2 require = 1 mole of O_2

Thus 0.34 moles of SO_2 will require=\frac{1}{2}\times 0.34=0.17moles  of O_2

Thus SO_2 is the limiting reagent as it limits the formation of product and O_2 is the excess reagent.

Moles of O_2 left = (0.68-0.17) mol = 0.51 mol

Mass of O_2=moles\times {\text {Molar mass}}=0.51moles\times 32g/mol=16.32g

Thus 16.32 g of O_2 as excess reagent are left.

3 0
2 years ago
What is the concentration of each type of monosaccharide in lactose
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Answer:

Lactose comprises the monosaccharides glucose and galactose and maltose, comprising two glucose molecules, which occurs in barley, wheat, and malt.

Explanation:

5 0
2 years ago
In which pair is the one on the left larger than the one on the right?
GarryVolchara [31]
K because parent atoms are always larger than their cations(positively charged atoms)
3 0
2 years ago
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A ___ such as h20 is a symbol that shows the elements in a compound and the ratio of atoms
KATRIN_1 [288]
I think the answer is 15
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3 years ago
450g of chromium(iii) sulfate reacts with excess potassium phosphate. How many grams of potassium sulfate will be produced? (ANS
Irina18 [472]

Answer:

600 g K₂SO₄

Explanation:

First write down the complete, balanced chemical equation for such question. In this case:

Cr₂(SO₄)₃ + 2K₃PO₄ →  3K₂SO₄ + 2CrPO₄

Next, calculate molar masses of required compounds mentioned in the question. In this case it is for Cr₂(SO₄)₃ and K₂SO₄.

  • Molar mass(MM) of Cr₂(SO₄)₃:

        = 2*(MM of Cr) + 3*( MM of S) + 3*4*( MM of O)

        = 2*(52) + 3*(32) + 12*(16)

        = 104 + 96 + 192

        = 392 g

  • Molar mass(MM) of K₂SO₄:

        = 2*(MM of K) + 1*( MM of S) + 4*( MM of O)

        = 2*(39) + 32 + 4*(16)

        = 78 + 32 + 64

        = 174 g

Here comes the concept of Limiting reagent:

The limiting reagent in a chemical reaction is the substance that is totally consumed when the chemical reaction is complete. The amount of product formed is limited by this reagent, since the reaction cannot continue without it. The other reactants present with this are usually in excess and called excess reactants. If quantities of both the reactants are given, then one should apply unitary method and find out the limiting reagent out of the two. Then, determine the amount of product formed or percentage yield.

Also, 1 mole( 392 g) of Cr₂(SO₄)₃ gives 3 moles( 174*3 = 522 g) of K₂SO₄.

Using unitary method, if 392g of Cr₂(SO₄)₃ gives 522 g of K₂SO₄ , then 450 g of Cr₂(SO₄)₃ will give how much of K₂SO₄?

Yeild of K₂SO₄ : \frac{522 * 450}{392}

That is 599.3 g.

Since we have not considered molecular masses of individual atoms to 6 decimal places, this number can be approximated to 600g.

Therefore, 600g of K₂SO₄ is produced.

6 0
3 years ago
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