First, we write the reaction equation:
2KI + PbNO₃ → K₂NO₃ + PbI₂
The molar ratio of KI to PbNO₃ is 2 : 1
Moles of PbNO₃ present:
Moles = concentration (M) x volume (dm³)
= 0.194 x 0.195
= 0.038
Moles of KI required = 2 x 0.038 = 0.076 moles
concentration = moles / volume
volume = moles / concentration
= 0.076 / 0.2
= 0.38 L = 380 ml
Hrxn = Q reaction / mol of reaction
mol of reaction = M * V = 10 * 1 = 10 mmol = 0.01 mol
Q water = m * C * (Tf - Ti)
= (10 + 10) (4.184) (26-20) = 502.08 J
Q reaction = - Q water = -502.08 J
Hrxn = -502.08 / (0.01) = - 50208 J = - 50.21 kJ/mol
Answer:
ΔG = 16.218 KJ/mol
Explanation:
- dihydroxyacetone phosphate ↔ glyceraldehyde-3-phosphate
∴ ΔG° = 7.53 KJ/mol * ( 1000 J / KJ ) = 7530 J/mol
∴ R = 8.314 J/K.mol
∴ T = 298 K
∴ Q = [glyceraldehyde-3-phosphate] / [dihydroxyacetone phosphate]
⇒ Q = 0.00300 / 0.100 = 0.03
⇒ ΔG = 7530J/mol - (( 8.314 J/K.mol) * ( 298 K ) * Ln ( 0.03 ))
⇒ ΔG = 16217.7496 J/mol ( 16.218 KJ/mol )
B. A solar cycle usually lasts 11 years.