Answer:
New volume is 25.0 mL
Explanation:
Let's assume the gas sample behaves ideally.
According to combined gas law for an ideal gas-
where, 
and 
represent initial and final pressure respectively
and 
represent initial and final volume respectively
and 
represent initial and final temperature (in kelvin) respectively
Here, 
, 
, 
and 
So, 
So, the new volume is 25.0 mL
Answer : The fraction of carbonic acid present in the blood is 5.95%
Explanation :
The mixture consists of carbonic acid ( H₂CO₃) and bicarbonate ion ( HCO₃⁻). This represents a mixture of weak acid and its conjugate which is a buffer.
The pH of a buffer is calculated using Henderson equation which is given below.
![pH = pKa + log \frac{[Base]}{[Acid]}](https://tex.z-dn.net/?f=pH%20%3D%20pKa%20%2B%20log%20%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D)
We have been given,
pH = 7.5
pKa of carbonic acid = 6.3
Let us plug in the values in Henderson equation to find the ratio Base/Acid.
![7.5 = 6.3 + log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=7.5%20%3D%206.3%20%2B%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![1.2 = log \frac{[base]}{[acid]}](https://tex.z-dn.net/?f=1.2%20%3D%20log%20%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D)
![\frac{[Base]}{[Acid]} = 10^{1.2}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2010%5E%7B1.2%7D)
![\frac{[Base]}{[Acid]} = 15.8](https://tex.z-dn.net/?f=%5Cfrac%7B%5BBase%5D%7D%7B%5BAcid%5D%7D%20%3D%2015.8)
![[Base] = 15.8 \times [Acid]](https://tex.z-dn.net/?f=%5BBase%5D%20%3D%2015.8%20%5Ctimes%20%5BAcid%5D)
The total of mole fraction of acid and base is 1. Therefore we have,
![[Acid] + [Base] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%20%5BBase%5D%20%3D%201)
But Base = 15.8 x [Acid]. Let us plug in this value in above equation.
![[Acid] + 15.8 \times [Acid] = 1](https://tex.z-dn.net/?f=%5BAcid%5D%20%2B%2015.8%20%5Ctimes%20%5BAcid%5D%20%3D%201)
![16.8 [Acid] = 1](https://tex.z-dn.net/?f=16.8%20%5BAcid%5D%20%3D%201)
![[Acid] = \frac{1}{16.8}](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%20%5Cfrac%7B1%7D%7B16.8%7D)
![[Acid] = 0.0595](https://tex.z-dn.net/?f=%5BAcid%5D%20%3D%200.0595)
[Acid] = 0.0595 x 100 = 5.95 %
The fraction of carbonic acid present in the blood is 5.95%
Answer:
The equilibrium constant for the reversible reaction = 0.0164
Explanation:
At equilibrium the rate of forward reaction is equal to the rate of backwards reaction.
The reaction is given as
A ⇌ B
Rate of forward reaction is first order in [A] and the rate of backward reaction is also first order in [B]
The rate of forward reaction = |r₁| = k₁ [A]
The rate of backward reaction = |r₂| = k₂ [B]
(Taking only the magnitudes)
where k₁ and k₂ are the forward and backward rate constants respectively.
k₁ = 0.010 s⁻¹
k₂ = 0.0610 s⁻¹
|r₁| = 0.010 [A]
|r₂| = 0.016 [B]
At equilibrium, the rate of forward and backward reactions are equal
|r₁| = |r₂|
k₁ [A] = k₂ [B] (eqn 1)
Note that equilibrium constant, K, is given as
K = [B]/[A]
So, from eqn 1
k₁ [A] = k₂ [B]
[B]/[A] = (k₁/k₂) = (0.01/0.0610) = 0.0163934426 = 0.0164
K = [B]/[A] = (k₁/k₂) = 0.0164
Hope this Helps!!!
Ivan Pavlov is most known for demonstrating conditioned lreflex in dogs.
<h3>what is conditioned reflex?</h3>
Conditioned reflex is a reflex action which has been conditioned to occur even without the stimulus which produces the reflex.
Ivan Pavlov is known to demonstrate conditioned reflex in dogs.
In his experiment, he trained dogs to salivate at the sound of a bell even if food which is the stimulus that produces salvation was not present.
Learn more about conditioned reflex at: brainly.com/question/24968947
A. 2
The dash represents two electrons
