<u>Ans: Acetic acid = 90.3 mM and Sodium acetate = 160 mM</u>
Given:
Acetic Acid/Sodium Acetate buffer of pH = 5.0
Let HA = acetic acid
A- = sodium acetate
Total concentration [HA] + [A-] = 250 mM ------(1)
pKa(acetic acid) = 4.75
Based on Henderson-Hasselbalch equation
pH = pKa + log[A-]/[HA]
[A-]/[HA] = 10^(pH-pKa) = 10^(5-4.75) = 10^0.25 = 1.77
[A-] = 1.77[HA] -----(2)
From (1) and (2)
[HA] + 1.77[HA] = 250 mM
[HA] = 250/2.77 = 90.25 mM
[A-] = 1.77(90.25) = 159.74 mM
In this item, we are simply to find the ions that may bond and are able to form a formula unit. We are also instructed to give out their name. There are numerous possible combinations of ions to form a compound. Some answers are given in the list below.
1. Na⁺ , Cl⁻ , NaCl ---> sodium chloride (this is most commonly known as table salt)
2. C⁴⁺ , O²⁻ , CO₂ ---> carbon dioxide
3. Al³+ , Cl⁻ , AlCl₃ ----> aluminum chloride
4. Ca²⁺ , Cl⁻ , CaCl₂ ---> calcium chloride
5. Li⁺ , Br⁻ , LiBr ---> lithium bromide
6. Mg³⁺ , O²⁻ , Mg₂O₃ ----> magnesium oxide
7. K⁺ , I⁻ , KI ---> potassium iodide
8. H⁺ , Cl⁻ , HCl --> hydrogen chloride
9. H⁺ , Br⁻ , HBr ----> hydrogen bromide
10. Na⁺ , Br⁻ , NaBr ---> sodium bromide
