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The reaction 2NO(g)+O2(g)−→−2NO2(g) is second order in NO and first order in O2. When [NO]=0.040M, and [O2]=0.035M, the observed

Oksanka [162]

Answer:

(a) The rate of disappearance of $O_{2}$ is: $4.65*10^{-5}$ M/s

(b) The value of rate constant is: 0.83036 $M^{-2}s^{-1}$

(c) The units of rate constant is: $M^{-2}s^{-1}$

(d) The rate will increase by a factor of 3.24

Explanation:

The rate of a reaction can be expressed in terms of the concentrations of the reactants and products in accordance with the balanced equation.

For the given reaction:

$2NO(g)+O_{2}->2NO_{2}$

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = $-\frac{d}{dt}[O_{2}]$ = $\frac{1}{2}\frac{d}{dt}[NO_{2}]$ -----(1)

According to the question, the reaction is second order in NO and first order in $O_{2}$ .

Then we can say that, rate = k $[NO]^{2}[O_{2}]$ -----(2)

where k is the rate constant.

The rate of disappearance of NO is given:

$-\frac{d}{dt}[NO]$ = $9.3*10^{-5}$ M/s.

(a) From (1), we can get the rate of disappearance of $O_{2}$ .

Rate of disappearance of $O_{2}$ = $-\frac{d}{dt}[O_{2}]$ = (0.5)*( $9.3*10^{-5}$ ) M/s = $4.65*10^{-5}$ M/s.

(b) The rate of the reaction can be obtained from (1).

rate = $-\frac{1}{2} \frac{d}{dt}[NO]$ = (0.5)*( $9.3*10^{-5}$ )

rate = $4.65*10^{-5}$ M/s

The value of rate constant can be obtained by using (2).

rate constant = k = $\frac{rate}{[NO]^{2}[O_{2}]}$

k = $\frac{4.65*10^{-5}}{(0.040)^{2}(0.035)}$ = 0.83036 $M^{-2}s^{-1}$

(c) The units of the rate constant can be obtained from (2).

k = $\frac{rate}{[NO]^{2}[O_{2}]}$

Substituting the units of rate as M/s and concentrations as M, we get:

$\frac{Ms^{-1} }{M^{3}}$ = $M^{-2}s^{-1}$

(d) The reaction is second order in NO. Rate is proportional to square of the concentration of NO.

$rate\alpha [NO]^{2}$

If the concentration of NO increases by a factor of 1.8, the rate will increase by a factor of $(1.8)^{2}$ = 3.24

5 0

3 years ago

What volume of oxygen gas is needed to completely combust 0.202L of butane (C4H10) gas?

saveliy_v [14]

Answer:

look at the file :)

Explanation:

4 0

3 years ago

Use the equation editor or "Insert Chemistry - WIRIS editor" to write the balanced molecular chemical equation for the reaction

11Alexandr11 [23.1K]

Answer:

<u>Balanced equation:</u>

$Pb(NO_{3})_{2}(aq)+K_{2}CO_{3}(aq)\rightarrow PbCO_{3}(s)+2KNO_{3}(aq)$

Explanation:

The chemical reaction between Lead(II) Nitrate and potassium carbonate is as follows.

$Lead(II)Nitrate+Potassium\,carbonate \rightarrow Lead(III)\,\,carbonate+Potassium\,nitrate$

$Pb(NO_{3})_{2}(aq)+K_{2}CO_{3}(aq)\rightarrow PbCO_{3}(s)+2KNO_{3}(aq)$

<u>Ionic equation:</u>

$Pb^{2+}(aq)+2NO_{3}^{-}(aq)+2K^{+}(aq)+CO_{3}^{2-}(aq)\Leftrightarrow PbCO_{3}(s)+K^{+}(aq)+2NO_{3}^{-}$

Cancel the same ions on the both sides of the reaction.

The net ionic equation is as follows.

$Pb^{2+}(aq)+CO_{3}^{2-}(aq)\Leftrightarrow PbCO_{3}(s)$

4 0

3 years ago

In the gold foil experiment, what was observed

natima [27]

Rutherford's Gold Foil Experiment proved the existence of a small massive center to atoms, which would later be known as the nucleus of an atom. Ernest Rutherford, Hans Geiger and Ernest Marsden carried out their Gold Foil Experiment to observe the effect of alpha particles on matter.

8 0

3 years ago

What is the volume of the liquid in the this diagram?<br>Would it be 37 mL or 36.5 mL?

vivado [14]

The volume of the liquid in this diagram shown above would be equal to 36.5 mL.

<h3>What is a graduated cylinder?</h3>

A graduated cylinder is also known as measuring cylinder and it can be defined as a narrow, cylindrical piece of laboratory equipment with marked lines, which are used to measure the volume of a liquid.

In order to take a reading for the measurement of the volume of a liquid such as water, you should ensure that your eye level is even with the center of the meniscus.

In this scenario, the volume of the liquid in this diagram would be 36.5 mL because each of the small lines on the graduated cylinder measures 0.5 mL.

Read more on graduated cylinder here: brainly.com/question/24869562

#SPJ1

8 0

2 years ago