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3 years ago

KFell Fe"(CN), + e + Nat → KNaFe'Fe(CN)6

Chemistry

1 answer:

Alinara [238K]3 years ago

7 0

Answer:

Most common oxidation states: +2, +3

M.P. 1535º

B.P. 2750º

Density 7.87 g/cm3

Characteristics: Iron is a gray, moderately active metal.

Characteristic reactions of Fe²⁺ and Fe³⁺

The [Fe(H2O)6]3+ ion is colorless (or pale pink), but many solutions containing this ion are yellow or amber-colored because of hydrolysis. Iron in both oxidation states forms many complex ions.

Aqueous Ammonia

Aqueous ammonia reacts with Fe(II) ions to produce white gelatinous Fe(OH)2, which oxidizes to form red-brown Fe(OH)3:

Fe2+(aq)+2NH3(aq)+3H2O(l)↽−−⇀Fe(OH)2(s)+2NH+4(aq)(1)

Fe3appt.gif

Aqueous ammonia reacts with Fe(III) ions to produce red-brown Fe(OH)3:

Fe3+(aq)+3NH3(aq)+3H2O(l)↽−−⇀Fe(OH)3(s)+3NH+4(aq)(2)

Fe3bppt.gif

Both precipitates are insoluble in excess aqueous ammonia. Iron(II) hydroxide quickly oxidizes to Fe(OH)3 in the presence of air or other oxidizing agents.

Sodium Hydroxide

Sodium hydroxide also produces Fe(OH)2 and Fe(OH)3 from the corresponding oxidation states of iron in aqueous solution.

Fe2+(aq)+2OH−(aq)↽−−⇀Fe(OH)2(s)(3)

Fe4appt.gif

Fe3+(aq)+3OH−(aq)↽−−⇀Fe(OH)3(s)(4)

Fe4bppt.gif

Neither hydroxide precipitate dissolves in excess sodium hydroxide.

Potassium Ferrocyanide

Potassium ferrocyanide will react with Fe3+ solution to produce a dark blue precipitate called Prussian blue:

K+(aq)+Fe3+(aq)+[Fe(CN)6]4−(aq)↽−−⇀KFe[Fe(CN)6](s)(5)

Fe5a1ppt.gif

With Fe2+ solution, a white precipitate will be formed that will be converted to blue due to the oxidation by oxygen in air:

2Fe2+(aq)+[Fe(CN)6]4−(aq)↽−−⇀Fe2[Fe(CN)6](s)(6)

Fe5a2ppt.gif

Many metal ions form ferrocyanide precipitates, so potassium ferrocyanide is not a good reagent for separating metal ions. It is used more commonly as a confirmatory test.

Potassium Ferricyanide

Potassium ferricyanide will give a brown coloration but no precipitate with Fe3+. With Fe2+, a dark blue precipitate is formed. Although this precipitate is known as Turnbull's blue, it is identical with Prussian blue (from Equation 5).

K+(aq)+Fe+2(aq)+[Fe(CN)6]3−(aq)↽−−⇀KFe[Fe(CN)6](s)(7)

Fe5b.gif

Potassium Thiocyanate

KSCN will give a deep red coloration to solutions containing Fe3+:

Fe+3(aq)+NCS−(aq)↽−−⇀[FeNCS]+2(aq)(8)

Fe5cppt.gif

No Reaction

Cl−, SO2−4

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Plants undergo photosynthesis to produce glucose according to the reaction below. What mass of water is required to produce 5.0g

solniwko [45]

Answer:

option a) 3 g

Explanation:

mass of Glucose = 5 g

Mass of H₂O = ?

Reaction Given:

6CO₂ + 6H₂O ----> C₆H₁₂O₆ + 6O₂

Solution:

First we have to find mass of glucose from balanced reaction.

So,

Look at the reaction

6CO₂ + 6H₂O -------> C₆H₁₂O₆ + 6O₂

6 mol 1 mol

As 6 mole of water (H₂O) give 1 mole of Glucose (C₆H₁₂O₆ )

Convert moles to mass

molar mass of C₆H₁₂O₆ = 6(12) + 12(1) + 6(16)

molar mass of C₆H₁₂O₆ = 72 + 12 + 96

molar mass of C₆H₁₂O₆= 180 g/mol

molar mass of H₂O = 2(1) + 16 = 18 g/mol

Now

6CO₂ + 6H₂O ---------> C₆H₁₂O₆ + 6O₂

6 mol (18 g/mol) 1 mol (180 g/mol)

108 g 180 g

108 g of water (H₂O) produce 180 g of glucose (C₆H₁₂O₆)

if 108 g of water (H₂O) produce 180 g of glucose (C₆H₁₂O₆) so how many grams of water (H₂O) will be required to produce 5 g of glucose (C₆H₁₂O₆).

Apply Unity Formula

108 g of water (H₂O) ≅ 180 g of glucose (C₆H₁₂O₆)

X g of water (H₂O) ≅ 5 g of glucose (C₆H₁₂O₆)

Do cross multiply

mass of water (H₂O) = 108 g x 5 g / 180 g

mass of water (H₂O) = 3 g

So 3 g of water is required to produce 5 g of glucose.

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Answer:

See Explanation

Explanation:

An ionic bond occurs due to electrostatic attraction between a positively charged ion and a negatively charged ion.

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The formation of coordinate bonds is evident when neutral molecules or negative ions with non bonding electrons donate same to empty metal orbitals. This is sometimes shown by an arrow pointing from the ligands to the metal center.

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Which model was proposed as a result of Rutherford's scattering experiment where positive particles did not pass straight throug

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Answer:

the nuclear model of the atom

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A stover-to-ethanol plant produces 40,000 tonne/yr of ethanol and contains 8functionalunits:feedstockhandling,pretreatment,simul

Step2247 [10]

Answer:

$FCI=458000*8*40000^{0.3}\\FCI=880818398.52 M$

FCI=88.0818 MM≅88 MM

Explanation:

Empirical correlation based on the work of Bridgwater and Mumford (1979):

For Liquid or solid phase Plants:

$FCI=458000*N*F^{0.3}$ F<60,000 tonne/yr Eq (1)

$FCI=7000*N*F^{0.68}$ F≥60,000 tonnes/yr Eq (2)

Where:

N is the number of functional units

F is the process throughput tonnes/yr

In our case F=40,000 tonne/yr <60,000 tonne/yr, We are going to use Eq (1)

$FCI=458000*N*F^{0.3}$ F<60,000 tonne/yr

N=8, F=40,000 tonne/yr

$FCI=458000*8*40000^{0.3}\\FCI=880818398.52 M$

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