They are different by a phase shift of pi/2
To be able to write correctly the equilibrium expression of a reaction, we need to know the balanced reaction and the phases of the substances in the reaction. When substances are solid, pure liquid they are not included in the expression. We do as follows:
<span>4KO2(s) + 2H2O(g) = 4KOH(s) + 3O2(g)
K = [O2]^3 / [H2O]^2</span>
Answer:
Frequency = 6.16 ×10¹⁴ Hz
λ = 4.87×10² nm
Explanation:
In case of hydrogen atom energy associated with nth state is,
En = -13.6/n²
For n = 2
E₂ = -13.6 / 2²
E₂ = -13.6/4
E₂ = -3.4 ev
Kinetic energy of electron = -E₂ = 3.4 ev
For n = 4
E₄ = -13.6 / 4²
E₄ = -13.6/16
E₄ = -0.85 ev
Kinetic energy of electron = -E₄ = 0.85 ev
Wavelength of radiation emitted:
E = hc/λ = E₄ - E₂
hc/λ = E₄ - E₂
by putting values,
6.63×10⁻³⁴Js × 3×10⁸m/s / λ = -0.85ev - (-3.4ev )
6.63×10⁻³⁴ Js× 3×10⁸m/s / λ = 2.55 ev
λ = 6.63×10⁻³⁴ Js× 3×10⁸m/s /2.55ev
λ = 6.63×10⁻³⁴ Js× 3×10⁸m/s /2.55× 1.6×10⁻¹⁹ J
λ = 19.89 ×10⁻²⁶ Jm / 2.55× 1.6×10⁻¹⁹ J
λ = 19.89 ×10⁻²⁶ Jm / 4.08×10⁻¹⁹ J
λ = 4.87×10⁻⁷ m
m to nm:
4.87×10⁻⁷ m ×10⁹nm/1 m
4.87×10² nm
Frequency:
Frequency = speed of electron / wavelength
by putting values,
Frequency = 3×10⁸m/s /4.87×10⁻⁷ m
Frequency = 6.16 ×10¹⁴ s⁻¹
s⁻¹ = Hz
Frequency = 6.16 ×10¹⁴ Hz
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