Answer: The most likely partial pressures are 98.7MPa for NO₂ and 101.3MPa for N₂O₄
Explanation: To determine the partial pressures of each gas after the increase of pressure, it can be used the equilibrium constant Kp.
For the reaction 2NO₂ ⇄ N₂O₄, the equilibrium constant is:
Kp = 
where:
P(N₂O₄) and P(NO₂) are the partial pressure of each gas.
Calculating constant:
Kp = 
Kp = 0.0104
After the weights, the total pressure increase to 200 MPa. However, at equilibrium, the constant is the same.
P(N₂O₄) + P(NO₂) = 200
P(N₂O₄) = 200 - P(NO₂)
Kp =
0.0104 = ![\frac{200 - P(NO_{2}) }{[P(NO_{2} )]^{2}}](https://tex.z-dn.net/?f=%5Cfrac%7B200%20-%20P%28NO_%7B2%7D%29%20%20%7D%7B%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D%7D)
0.0104![[P(NO_{2} )]^{2}](https://tex.z-dn.net/?f=%5BP%28NO_%7B2%7D%20%29%5D%5E%7B2%7D)
+ 
- 200 = 0
Resolving the second degree equation:
= 
= 98.7
Find partial pressure of N₂O₄:
P(N₂O₄) = 200 - P(NO₂)
P(N₂O₄) = 200 - 98.7
P(N₂O₄) = 101.3
The partial pressures are = 98.7 MPa and P(N₂O₄) = 101.3 MPa
Answer: The pressure of a gas will increase when there is a decrease in the volume of the gas.
Explanation: according to Boyle's law, the volume of a gas will decrease when the pressure is increased at constant temperature and vice versa.
Hi, you have not provided structure of the aldehyde and alkoxide ion.
Therefore i'll show a mechanism corresponding to the proton transfer by considering a simple example.
Explanation: For an example, let's consider that proton transfer is taking place between a simple aldehyde e.g. acetaldehyde and a simple alkoxide base e.g. methoxide.
The hydrogen atom attached to the carbon atom adjacent to aldehyde group are most acidic. Hence they are removed by alkoxide preferably.
After removal of proton from aldehyde, a carbanion is generated. As it is a conjugated carbanion therefore the negative charge on carbon atom can conjugate through the carbonyl group to form an enolate which is another canonical form of the carbanion.
All the structures are shown below.
Al3+ is cation due to its positve charge
N3- is an anion due to its negative charge
B) hydrogen gas burns in air.
explanation: the rest are physical properties.
