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An orbital that penetrates into the region occupied by core electrons is less shielded from nuclear charge than an orbital that does not penetrate and therefore has a lower energy.
Explanation:
The only true statement from the given options is that "an orbital that penetrates into the region occupied by core electrons is less shielded from nuclear charge than an orbital that does not penetrate and therefore has a lower energy." Inner orbitals which are also known to contain core electrons feels the bulk of the nuclear pull on them compared to the outermost orbitals containing the valence electrons.
- The nuclear pull is the effect of the nucleus pulling and attracting the electrons in orbitals.
- This pull is stronger for inner orbitals and weak on the outer ones.
- The outer orbitals are said to be well shielded from the pull of the nuclear charge.
- Also, based on the quantum theory, electrons in the outer orbitals have higher energies because they occupy orbitals at having higher energy value.
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Answer: The rate constant for the reaction is 
Explanation:
Expression for rate law for first order kinetics is given by:
where,
k = rate constant
t = age of sample = 559 min
a = let initial amount of the reactant = 
a - x = amount left after decay process = 
The rate constant for the reaction is
Answer:
A reaction is non-spontaneous at any temperature when the Gibbs free energy > 0.
Explanation:
There is a state function, that determines if a reaction is sponaneous or non spontaneous:
ΔG = Gibbs free energy
A reaction is non spontaneous when it does require energy to produce that reaction. It will be spontaneous, when the reaction does not require energy to be occured.
The formula is: ΔG = ΔH - T.ΔS
ΔH → Enthalpy → Energy gained or realeased as heat.
ΔH < 0 → <em>Exothermic reaction. Spontaneity is favored
</em>
T → Temperature
ΔS → Entropy → Degree of disorder of a system.
When the system has a considered disorder ΔS > 0, disorder increases.
When the system is more ordered, ΔS < 0, disorder decreases.
The reaction will be non spontaneous if, the enthalpy is positive (endothermic reaction) and the ΔS < 0 (disorder decreases). It will not occur if we do not give energy.
ΔG < 0 → Spontaneous reaction
ΔG > 0 → Non spontaneous reaction
ΔG = 0 → System in equilibrium
