Answer:
Total Kcal energy produced in the catabolism of mannoheptulose = 1184 Kcal
Explanation:
The molecular formula of mannoheptulose is C₇H₁₄O₇.
The structure is as shown in the attachment below.
Number of C-C bonds present in mannoheptulose = 6
Number of C-H bonds present in mannoheptulose = 8
Since the each C-C bond contains 76 Kcal of energy,
Amount of energy present in six C-C bonds = 6 * 76 = 456 Kcal
Also, since each C-H bond contains 91 Kcal of energy;
amount of energy present in eight C-H bonds = 8 * 91 = 728 Kcal
Total Kcal energy produced in the catabolism of mannoheptulose = 456 + 728 = 1184 Kcal
1. Find its coordination figure/coordination number of central atom (CF)
Ev = Vallence electron of central atom
Σe = electrons donated from substituents
Terminal O gives 0 electrons, hence Σe = 3 x 0
charge = charge of the compound
2. Find EP (electron pairs) and LP (lone pairs)
LP = CF - EP
3. Draw the skeleton with octet substituents (top right figure)
4. Find formal charge for each atoms (Qf)
5. Write formal charge near atom in skeleton
6. Enjoy
1. The molar mass of Fe2(CO3)3 is 291.72 g/mol. This means that 45.6 g is equivalent to 0.156 mol. Dividing by the 0.167 L of water gives a solution of 0.936 M.
2. Multiplying (0.672 M)(0.025 L) = 0.0168 mol. The molar mass of Ni(OH)2 is 92.71 g/mol, so multiplying by 0.0168 mol = 1.56 grams. Therefore you would need to dissolved 1.56 g of Ni(OH)2 into 25 mL of water.
3. Fe2(CO3)3 + Ni(OH)2 --> Fe(OH)3 + NiCO3Balancing: Fe2(CO3)3 + 3Ni(OH)2 --> 2Fe(OH)3 + 3NiCO3The reaction quotient is:[Fe(OH)3]^2 * [NiCO3]^3 / [Fe2(CO3)3][Ni(OH)2]^3= (0.05)^2 * (1.45)^3 / (0.936)(0.672)^3= 0.0268Since this is < 1, it implies that the reactants are favored at equilibrium.
Explanation:
The given data is as follows.
P = 3 atm
=
= 
= 9 L =
(as 1 L = 0.001
),
= 15 L = 
Heat energy = 800 J
As relation between work, pressure and change in volume is as follows.
W = 
or, W = 
Therefore, putting the given values into the above formula as follows.
W = 
= 
= 1823.85 Nm
or, = 1823.85 J
As internal energy of the gas
is as follows.
= Q - W
= 800 J - 1823.85 J
= -1023.85 J
Thus, we can conclude that the internal energy change of the given gas is -1023.85 J.