Answer is: Ksp for silver sulfide is 8.00·10⁻⁴⁸.
Reaction
of dissociation: Ag₂S(s) → 2Ag⁺(aq) + S²⁻(aq)<span>.
</span>s(Ag₂S) = s(S²⁻) = 1.26·10⁻¹⁶ M.
s(Ag⁺) = 2s(Ag₂S) = 2.52·10⁻¹⁶ M; equilibrium concentration of silver cations.
Ksp = s(Ag⁺)² · s(S²⁻).
Ksp = (2.52·10⁻¹⁶ M)² · 1.26·10⁻¹⁶ M.
Ksp = 6.35·10⁻³² M² · 1.26·10⁻¹⁶ M.
Ksp = 8.00·10⁻⁴⁸ M³.
Considering the definition of pOH and strong base, the pOH of the aqueous solution is 1.14
The pOH (or potential OH) is a measure of the basicity or alkalinity of a solution and indicates the concentration of ion hydroxide (OH-).
pOH is expressed as the logarithm of the concentration of OH⁻ ions, with the sign changed:
pOH= - log [OH⁻]
On the other hand, a strong base is that base that in an aqueous solution completely dissociates between the cation and OH-.
LiOH is a strong base, so the concentration of the hydroxide will be equal to the concentration of OH-. This is:
[LiOH]= [OH-]= 0.073 M
Replacing in the definition of pOH:
pOH= -log (0.073 M)
<u><em>pOH= 1.14 </em></u>
In summary, the pOH of the aqueous solution is 1.14
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Answer:
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Balance each one by adding electrons to make the charges on both sides the same:
Sn--> Sn2+ + 2 e-
Ag+ + 1 e- --> Ag
Now, you have to have the same number of electrons in the two half-reactions, so multiply the second one by 2 to get:
2 Ag+ + 2 e- --> 2 Ag
Now, just add the two half reactions together, cancelling anything that's the same on both sides:
2 Ag+ + Sn --> Sn2+ + 2 Ag
And you're done.