Answer 2.04
Explanation
Electronegativity decreases down the group and increases across the period in the periodic table.
In the period two of the periodic table,we have the following values for electronegativities with respect to its elements.
Li...........0.98
Be.........1.57
B..........2.04
C.........2.55
N..........3.04
O...........3.44
F...........3.98
Ne........n.a
The value that should be where M is is 2.04
The formula is m = D x V
D = <span>13.69 g/cm^3.
</span>V = <span>15.0 cm^3
the mass of the liquid mercury is m= </span>13.69 g/cm^3 x 15.0 cm^3 = 195g
the molar mass of Hg is 200,
1 mole of Hg = 200g Hg, so #mole of Hg= 195 / 200 = 0.97 mol
but we know that
1 mole = 6.022 E23 atoms
0.97 mole=?
6.022 E23 atoms x 0.97 / 1 mole = 5.84 E23 atoms
ΔG⁰ = ΔH⁰ - TΔS
ΔH⁰ = Hf,(CH₃OH) - Hf,(CO) = -238.7 + 110.5 = -128.2 kJ/mol
ΔS = S(CH₃OH) - S(CO) - 2S(H₂) = 126.8 - 197.7 - 2 x 130.6 = -332.1 J/mol.K
So
ΔG⁰ = - 128200 + 332.1 T
For the reaction to be spontaneous:
ΔG⁰ < 0
So: -128200 + 332.1 T < 0
332.1 T < 128200
T < 386.028 K
Answer is: the missing pressure is 1088.66 mmHg.
Gay-Lussac's Law states that the pressure of a given amount of gas held at constant volume is directly proportional to the Kelvin temperature.
p₁/T₁ = p₂/T₂.
p₁ = 960 mmHg; pressure of the gas.
T₁ = 100°C + 273.15.
T₁ = 373.15 K; temperature of the gas.
T₂ = 150°C + 273.15.
T₂ = 423.15 K.
p₂ = p₁T₂/T₁.
p₂ = 960 mmHg · 423.15 K / 373.15 K.
p₂ = 1088.66 mmHg.
