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3 years ago

What is the oxidation number of nitrogen in the nitrate ion NO3^1-

Chemistry

1 answer:

harina [27]3 years ago

5 0

Answer:

Explanation:

You use the rules for oxidation numbers to calculate that the oxidation number of N is +5.

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Your job is to determine the concentration of ammonia in a commercial window cleaner. In the titration of a 25.0 mL sample of th

ruslelena [56]

Answer:

The initial concentration of ammonia is 0.14 M and the pH of the solution at equivalence point is 5.20

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

$\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}$ .....(1)

Molarity of HCl solution = 0.164 M

Volume of solution = 23.8 mL = 0.0238 L (Conversion factor: 1 L = 1000 mL)

Putting values in equation 1, we get:

$0.164M=\frac{\text{Moles of HCl}}{0.0238L}\\\\\text{Moles of HCl}=(0.146mol/L\times 0.0238L)=0.0035mol$

The chemical equation for the reaction of ammonia and HCl follows:

$NH_3+HCl\rightarrow NH_4^++Cl^-$

By Stoichiometry of the reaction:

1 mole of HCl reacts with 1 mole of ammonia

So, 0.0035 moles of HCl will react with = $\frac{1}{1}\times 0.0035=0.0035mol$ of ammonia

Calculating the initial concentration of ammonia by using equation 1:

Moles of ammonia = 0.0035 moles

Volume of solution = 25 mL = 0.025 L

Putting values in equation 1, we get:

$\text{Initial concentration of ammonia}=\frac{0.0035mol}{0.025L}=0.14M$

By Stoichiometry of the reaction:

1 mole of ammonia produces 1 mole of ammonium ion

So, 0.0035 moles of ammonia will react with = $\frac{1}{1}\times 0.0035=0.0035mol$ of ammonium ion

Calculating the concentration of ammonium ion by using equation 1:

Moles of ammonium ion = 0.0035 moles

Volume of solution = [23.8 + 25] mL = 48.8 mL = 0.0488 L

Putting values in equation 1, we get:

$\text{Molarity of ammonium ion}=\frac{0.0035mol}{0.0488L}=0.072M$

To calculate the acid dissociation constant for the given base dissociation constant, we use the equation:

$K_w=K_b\times K_a$

where,

$K_w$ = Ionic product of water = $10^{-14}$

$K_a$ = Acid dissociation constant

$K_b$ = Base dissociation constant = $1.8\times 10^{-5}$

$10^{-14}=1.8\times 10^{-5}\times K_a\\\\K_a=\frac{10^{-14}}{1.8\times 10^{-5}}=5.55\times 10^{-10}$

The chemical equation for the dissociation of ammonium ion follows:

$NH_4^+\rightarrow NH_3+H^+$

The expression of $K_a$ for above equation follows:

$K_a=\frac{[NH_3][H^+]}{[NH_4^+]}$

We know that:

$[NH_3]=[H^+]=x$

$[NH_4^+]=0.072M$

Putting values in above expression, we get:

$5.55\times 10^{-10}=\frac{x\times x}{0.072}\\\\x=6.32\times 10^{-6}M$

To calculate the pH concentration, we use the equation:

$pH=-\log[H^+]$

We are given:

$[H^+]=6.32\times 10^{--6}M$

$pH=-\log (6.32\times 10^{-6})\\\\pH=5.20$

Hence, the initial concentration of ammonia is 0.14 M and the pH of the solution at equivalence point is 5.20

5 0

2 years ago

Two isotopes of the same element must have the same

emmainna [20.7K]

Answer:

atomic number

Explanation:

isotope is a family of an element with the same atomic number but different mass number.

3 0

2 years ago

Avogradro's number is the number of particles in one gram of carbon- 12 atom true or false?

LiRa [457]

Answer:

True

Explanation:

The value of the mole is equal to the number of atoms in exactly 12 grams of pure carbon-12. 12.00 g C-12 = 1 mol C-12 atoms = 6.022 × 1023 atoms • The number of particles in 1 mole is called Avogadro's Number (6.0221421 x 1023).

5 0

3 years ago

How many electrons will a fluorine (f) atom gain or lose in forming an ion?

777dan777 [17]

It will gain one electrons to form the fluorine ion

6 0

3 years ago

What is the net ionic equation for the reaction<br> ofFeCl3 and KOH in water?

Levart [38]

Answer:

Fe³⁺(aq) + 3 OH⁻(aq) → Fe(OH)₃(s)

Explanation:

First, we will write the molecular equation because it is the easiest to balance.

FeCl₃(aq) + 3 KOH(aq) → Fe(OH)₃(s) + 3 KCl(aq)

The full ionic equation includes all the ions and the molecular species.

Fe³⁺(aq) + 3 Cl⁻(aq) + 3 K⁺(aq) + 3 OH⁻(aq) → Fe(OH)₃(s) + 3 K⁺(aq) + 3 Cl⁻(aq)

The net ionic equation includes only the ions that participate in the reaction and the molecular species.

Fe³⁺(aq) + 3 OH⁻(aq) → Fe(OH)₃(s)

8 0

3 years ago

What is the oxidation number of nitrogen in the nitrate ion NO3^1-​

What is the oxidation number of nitrogen in the nitrate ion NO3^1-