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3 years ago

Consider a general reaction

Chemistry

1 answer:

choli [55]3 years ago

7 0

Answer:

a) K = 5.3175

b) ΔG = 3.2694

Explanation:

a) ΔG° = - RT Ln K

∴ T = 25°C ≅ 298 K

∴ R = 8.314 E-3 KJ/K.mol

∴ ΔG° = - 4.140 KJ/mol

⇒ Ln K = - ( ΔG° ) / RT

⇒ Ln K = - ( -4.140 KJ/mol ) / (( 8.314 E-3 KJ/K.mol )( 298 K ))

⇒ Ln K = 1.671

⇒ K = 5.3175

b) A → B

∴ T = 37°C = 310 K

∴ [A] = 1.6 M

∴ [B] = 0.45 M

∴ K = [B] / [A]

⇒ K = (0.45 M)/(1.6 M)

⇒ K = 0.28125

⇒ Ln K = - 1.2685

∴ ΔG = - RT Ln K

⇒ ΔG = - ( 8.314 E-3 KJ/K.mol )( 310 K )( - 1.2685 )

⇒ ΔG = 3.2694

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3 years ago

What volume of a 2.25 M sodium chloride solution will contain 4.58 moles of sodium chloride

Rzqust [24]

Answer:

Option E. 2.04 L

Explanation:

Data obtained from the question include:

Molarity of NaCl = 2.25 M

Mole of NaCl = 4.58 moles

Volume =..?

Molarity is simply defined as the mole of solute per unit litre of the solution. It is represented mathematically as:

Molarity = mole /Volume

With the above formula, we can obtain the volume of the solution as follow:

Molarity = mole /Volume

2.25 = 4.58/volume

Cross multiply

2.25 x volume = 4.58

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3 years ago

What is the theoretical yield of fluorenone if you oxidize 175 mg of fluorene?

My name is Ann [436]

Answer:

602 mg of CO₂ and 94.8 mg of H₂O

Explanation:

The yield is measured by the amount of each product produced by the reaction.

The chemical formula of fluorene is C₁₃H₁₀, and its molar mass is 166.223 g/mol.

The oxidation, also know as combustion, of this hydrocarbon is represented by the following balanced chemical equation:

$2C_{13}H_{10}+31O_2\rightarrow 26CO_2+10H_2O$

To calculate the yield follow these steps:

1. Mole ratio

$2molC_{13}H_{10}:31molO_2:26molCO_2:10molH_2O$

2. Convert 175mg of fluorene to number of moles

$175mg/times 1g/1,000mg=0.175g$

Number of moles = mass in grams / molar mass

$\text{number of moles}=0.175g/166.223g/mol=0.0010528mol$

3. Set a proportion for each product of the reaction

a) For CO₂

i) number of moles

$2molC_{10}H_{13}/26molCO_2=0.0010528molC_{10}H{13}/x$

$x=0.0010528molC_{10}H_{13}\times 26molCO_2/2molC_{10}H_{13}=0.013686molCO_2$

ii) mass in grams

The molar mass of CO₂ is 44.01g/mol

mass = number of moles × molar mass

mass = 0.013686 moles × 44.01 g/mol = 0.602 g = 602mg

b) For H₂O

i) number of moles

$0.0010528molC_{10}H_{13}\times10molH_2O/2molC_{10}H_{13}=0.00526molH_2O$

ii) mass in grams

The molar mass of H₂O is 18.015g/mol

mass = number of moles × molar mass

mass = 0.00526 moles × 18.015 g/mol = 0.0948mg = 94.8 mg

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