Answer:
[C₆H₅COO⁻][H₃O⁺]/[C₆H₅COOH] = Ka
Explanation:
The reaction of dissociation of the benzoic acid in water is given by the following equation:
C₆H₅-COOH + H₂O ⇄ C₆H₅-COO⁻ + H₃O⁺ (1)
The dissociation constant of an acid is the measure of the strength of an acid:
HA ⇄ A⁻ + H⁺ (2)
![K_{a} = \frac{[A^{-}][H^{+}]}{[HA]}](https://tex.z-dn.net/?f=%20K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BA%5E%7B-%7D%5D%5BH%5E%7B%2B%7D%5D%7D%7B%5BHA%5D%7D%20)
(3)
<em>Where the dissociation constant of the acid (Ka) is equal to the ratio of the concentration of the dissociated forms of the acid, [A⁻][H⁺], and the concentration of the acid, [HA]. </em>
So, starting from the equations (2) and (3), the constant equation for the dissociation reaction of benzoic acid in water, of the equation (1), is:
![K_{a} = \frac{[C_{6}H_{5}COO^{-}][H_{3}O^{+}]}{[C_{6}H_{5}COOH]}](https://tex.z-dn.net/?f=%20K_%7Ba%7D%20%3D%20%5Cfrac%7B%5BC_%7B6%7DH_%7B5%7DCOO%5E%7B-%7D%5D%5BH_%7B3%7DO%5E%7B%2B%7D%5D%7D%7B%5BC_%7B6%7DH_%7B5%7DCOOH%5D%7D%20)
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<span>An exothermic reaction is one in which heat is released from the reagents into the ambient environment. Perhaps somewhat counterintuitively, condensation is in fact an example of such a reaction. During the process of the gas-to-liquid phase change, water goes from a higher-energy to lower-energy state of matter, and, as such, releases heat into the environment.</span>
Answer:
Explanation:
C) What is the multiplicity of Proton-alpha's signal in this scenario when there are 2 identical protons "next door"?
Based on n+1 rule. Here n=2 (identical beta protons).
2+1=3
So the multiplicity of alpha proton is triplet, .
D) For molecules containing only single bonds (we'll discuss the influence of double bonds in a future lecture), what is the adjective that describes the position of protons that split a "next door neighbor's" signal?
The meaning of the adjective is this: the multiplicity of beta protons is singlet only (no spliting) in absence of alpha proton . But beta protons splits as doublet (n=1) in the presence of alpha proton,
E) How many bonds connect these "splitting next door neighbors"?
There are 3 bonds in between alpha and beta protons in a molecule.
F) What is the multiplicity of the Proton-betas' signal?
Following the n+1 rule, here n=1 (1 alpha proton) so 1+1=2. Hence it is a doublet.
Answer:
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