5.50 L of a 0.190 M CaCl2M CaCl2 solution How do you find Grams?

Chemistry

1 answer:

Firdavs [7]2 years ago

6 0

Answer:

115.891

Explanation:

Molarity is equal to moles/liters so to get moles we multiply molarity by liters, after this we multiply the moles by the total atomic weight of the compound to get grams

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Answer:

b. Second order in NO and first order in O₂.

Explanation:

A. The mechanism

$\rm 2NO\xrightarrow[k_{-1}]{k_{1}}N_{2}O_{2} \, (fast)\\\rm N_{2}O_{2} + O_{2}\xrightarrow{k_{2}} 2NO_{2} \, (slow)$

B. The rate expressions

$-\dfrac{\text{d[NO]} }{\text{d}t} = k_{1}[\text{NO]}^{2} - k_{-1} [\text{N}_{2}\text{O}_{2}]^{2}\\\\\rm -\dfrac{\text{d[N$_{2}$O$_{2}$]}}{\text{d}t} = -\dfrac{\text{d[O$_{2}$]}}{\text{d}t} = k_{2}[ N_{2}O_{2}][O_{2}] - k_{1} [NO]^{2}\\\\\dfrac{\text{d[NO$_{2}$]}}{\text{d}t}= k_{2}[ N_{2}O_{2}][O_{2}]$

The last expression is the rate law for the slow step. However, it contains the intermediate N₂O₂, so it can't be the final answer.

C. Assume the first step is an equilibrium

If the first step is an equilibrium, the rates of the forward and reverse reactions are equal. The equilibrium is only slightly perturbed by the slow leaking away of N₂O₂ to form product.

$\rm k_{1}[NO]^{2} = k_{-1} [N_{2}O_{2}]\\\\\rm [N_{2}O_{2}] = \dfrac{k_{1}}{k_{-1}}[NO]^{2}$