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The elements that form anions will have the electronic configuration similar to the noble gas that is in their period and those that form cations will have a configuration similar to that of the noble gas in the previous period.
He: Be
Ne: F, Al
Ar: Ca, P
Kr: Rb, Se
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M(P)=3.72 g
M(P)=31 g/mol
m(Cl)=21.28 g
M(Cl)=35.5 g/mol
n(P)=m(P)/M(P)
n(P)=3.72/31=0.12 mol
n(Cl)=m(Cl)/M(Cl)
n(Cl)=21.28/35.5=0.60 mol
P : Cl = 0.12 : 0.60 = 1 : 5
PCl₅ - is the empirical formula