Answer:
[Ag⁺] = 0.0666M
Explanation:
For the addition of Ag⁺ and CN⁻, the (Ag(CN)₂⁻ is produced, thus:
Ag⁺ + 2CN⁻ ⇄ Ag(CN)₂⁻
Kf = 1x10²¹ = [Ag(CN)₂⁻] / [CN⁻]² [Ag⁺]
As initial concentrations of Ag⁺ and CN⁻ are:
[Ag⁺] = 0.110L × (3.0x10⁻³mol / L) = 3.3x10⁻⁴mol / (0.110L + 0.230L) = 9.7x10⁻⁴M
[CN⁻] = 0.230L × (0.1mol / L) = 0.023mol / (0.110L + 0.230L) = 0.0676M
The equilibrium concentrations of each compound are:
[CN⁻] = 9.7x10⁻⁴M - x
[Ag⁺] = 0.0676M - x
[Ag(CN)₂⁻] = x
<em>Where x is reaction coordinate</em>
Replacing in Kf formula:
1x10²¹ = [x] / [9.7x10⁻⁴M - x]² [0.0676M - x]
1x10²¹ = [x] / 6.36048×10⁻⁸ - 0.000132085 x + 0.06954 x² - x³
-1x10²¹x³ + 6.954x10¹⁹x² - 1.32085x10¹⁷ x + 6.36x10¹³ = x
-1x10²¹x³ + 6.954x10¹⁹x² - 1.32085x10¹⁷ x + 6.36x10¹³ = 0
Solving for x:
X = 9.614x10⁻⁴M
Thus, equilibrium concentration of Ag⁺ is:
[Ag⁺] = 0.0676M - 9.614x10⁻⁴M = <em>0.0666M</em>
Answer:
doublet
Explanation:
Proton MNR is used for the determination of no. of equivalents protons in a molecule
In the molecule, single NMR signal is produced for each set of protons.
Signal splitting is called spin-spin coupling and the splitting of signals depends upon the no. of neighboring proton.
The no. of signal for a proton is equal to n+1, where n is neighboring protons.
In 1-bromo-2-methylpropane, neighboring proton for both methyl protons are one. But the chemical environment of both the methyl protons are different.
Neighboring proton for methyl protons = 1
No. of signal for methyl protons = 1+1 =2
Hence, two doublets will be generated for each set of methyl protons. protons.
Answer:
Conversion of kinetic energy to potential energy (chemo mechanical energy)
In the state of rest, the rubber is a tangled mass of long chained cross-linked polymer that due to their disorderliness are in a state of increased entropy. By pulling on the polymer, the applied kinetic energy stretches the polymer into straight chains, giving them order and reducing their entropy. The stretched rubber then has energy stored in the form of chemo mechanical energy which is a form of potential energy
Conversion of the stored potential energy in the stretched to kinetic energy
By remaining in a stretched condition, the rubber is in a state of high potential energy, when the force holding the rubber in place is removed, due to the laws of thermodynamics, the polymers in the rubber curls back to their state of "random" tangled mass releasing the stored potential energy in the process and doing work such as moving items placed in the rubber's path of motion such as an object that has weight, w then takes up the kinetic energy 1/2×m×v² which can can result in the flight of the object.
Explanation:
