The Law of Multiple Proportions states that if 2 elements form more than one compound between them, if the mass of one of the elements is fixed, the masses of the other element will be in a ratio of small whole numbers.
In this case, the two elements are Fe and Cl, and the 2 compounds are X and Y. Let us fix the mass of Fe in 1.00 g and analyze what happens with the masses of Cl.
For X:

For Y:

The ratio mCl in X/mCl in Y is 1.27g/1.91g = 0.664 ≅ 2/3. This is a ratio of small whole numbers, which proves the Law of Multiple Proportions.
2SO2(g)+O2(g)→2 SO3(g), here reaction entropy decreases as the number of gas moles decreases from reactions to products.
HCL(g)+NH3(g)→NH4CL(s), entropy decreases as molecules of gas are converted into solid.
CO2(s)→CO2(g), entropy increases as gas is formed from a solid.
Cao(s)+CO2(g)→Caco3(s), entropy increases as gas is converted into a solid.
Answer:
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I do believe the answer is A. Hope this helps.
Br2 or O2 or N2 or H2 or F2 or I2 etc.