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1 answer:
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Answer:
Kp = 0.022
Explanation:
<em>Full question: ...With 2.3 atm of ammonia gas at 32. °C. He then raises the temperature, and when the mixture has come to equilibrium measures the partial pressure of hydrogen gas to be 0.69 atm. </em>
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The equilibrium of ammonia occurs as follows:
2NH₃(g) ⇄ N₂(g) + 3H₂(g)
Where Kp is defined as:
<em>Where P represents partial pressure of each gas.</em>
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As initial pressure of ammonia is 2.3atm, its equilibrium concentration will be:
P(NH₃) = 2.3atm - 2X
<em>Where X represents reaction coordinate</em>
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Thus, pressure of hydrogen and nitrogen is:
P(N₂) = X
P(H₂) = 3X.
As partial pressure of hydrogen is 0.69atm:
3X = 0.69
X = 0.23atm:
P(NH₃) = 2.3atm - 2(0.23atm) = 1.84atm
P(N₂) = 0.23atm
P(H₂) = 0.69atm
Answer:
The four resonance structures of the phenoxide ion are shown in the image attached
The conjugate base of cyclohexanol has only one resonance contributor, while
the conjugate base of phenol has four resonance contributors.
Explanation:
In organic chemistry, it is known that structures are more stable if they possess more resonance contributors. The greater the number of contributing canonical structures, the more stable the organic specie. Since the phenoxide ion has four contributing canonical structures, it is quite much more stable than cyclohexanol having only one contributing structure to its conjugate base. Hence the PKa(acid dissociation constant) of phenol is lesser than that of cyclohexanol. The conjugate base of phenol is stabilized by resonance.
