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Sindrei [870]
3 years ago
13

What are conditions of cis trans isomerism, justify with example?

Chemistry
1 answer:
Bezzdna [24]3 years ago
3 0

Answer:

Conditions for geometrical isomerism: There are two necessary conditions for a compound to possess geometrical isomerism:

(i) It must contain a carbon-carbon double bond in the molecule.

(ii) Two unlike atoms or groups must be linked to each doubly bonded carbon atoms

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When the process goes under constant pressure (and assuming same number of moles),

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T₁/V₁=T₂/V₂

If V₂ = V₁(1+0.8) = 1.8V₁, then,

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If you do not assume ideal gas, you use the compressibility factor, z. The gas equation would now become

PV =znRT

However, we cannot solve this because we don't know the value of z₁ and z₂. There will be more unknowns than given so we won't be able to solve the problem. But definitely, the compressibility factor method is more accurate because it does not assume ideality.

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