All categories

2 years ago

What are conditions of cis trans isomerism, justify with example?

Chemistry

1 answer:

Bezzdna [24]2 years ago

3 0

Answer:

Conditions for geometrical isomerism: There are two necessary conditions for a compound to possess geometrical isomerism:

(i) It must contain a carbon-carbon double bond in the molecule.

(ii) Two unlike atoms or groups must be linked to each doubly bonded carbon atoms

You might be interested in

The combustion of gasoline produces carbon dioxide and water. Assume gasoline to be pure octane (C8H18) and calculate the mass (

Mnenie [13.5K]

Answer:

3.1 kg

Explanation:

Step 1: Write the balanced combustion equation

C₈H₁₈ + 12.5 O₂ ⇒ 8 CO₂ + 9 H₂O

Step 2: Calculate the moles corresponding to 1.0 kg of C₈H₁₈.

The molar mass of C₈H₁₈ is 114.23 g/mol.

1.0 × 10³ g × 1 mol/114.23 g = 8.8 mol

Step 3: Calculate the moles of CO₂ produced from 8.8 moles of C₈H₁₈

The molar ratio of C₈H₁₈ to CO₂ is 1:8. The moles of CO₂ produced are 8/1 × 8.8 mol = 70 mol.

Step 4: Calculate the mass corresponding to 70 moles of CO₂

The molar mass of CO₂ is 44.01 g/mol.

70 mol × 44.01 g/mol = 3.1 × 10³ g = 3.1 kg

5 0

3 years ago

A molecular covalent substance (such as co2) has a low melting point because the covalent bonds that hold the molecules together

Leona [35]

A molecular covalent substance (such as co2) has a low melting point because the covalent bonds that hold the molecules together are weak and do not require much energy to break:- False.

What are covalent bonds ?

An electron transfer that leads to the formation of electron pairs between atoms is known as a covalent bond. When atoms share electrons, a stable balance of the repulsive and attractive forces among them is known as covalent bonding. These electron pairs are also known as bonds or shared pairs.

It is a molecular compound, which is a mixture of at least two atoms—the smallest building blocks of matter—joined by a covalent bond. These atoms are joined by a covalent bond, which is formed when electrons are shared.

Learn more about covalent bond here:-

brainly.com/question/19382448

#SPJ4

6 0

2 years ago

How many grams of Br are in 335g of CaBr2

ASHA 777 [7]

The answer is 267.93 g

Molar mass of CaBr2 is the sum of atomic masses of Ca and Br:
Mr(CaBr2) = Ar(Ca) + 2Ar(Br)
Ar(Ca) = 40 g/mol
Ar(Br) = 79.9 g/mol
Mr(CaBr2) = 40 + 2 * 79.9 = 199.8 g/mol

The percentage of Br in CaBr2 is:
2Ar(Br) / Mr(CaBr2) * 100 = 2 * 79.9 / 199.8 * 100 = 79.98%

Now make a proportion:
x g in 79.98%
335 g in 100%
x : 79.98% = 335 g : 100%
x = 79.98% * 335 g : 100%
x = 267.93 g

7 0

3 years ago

s) Suppose we now collect hydrogen gas, H2(g), over water at 21◦C in a vessel with total pressure of 743 Torr. If the hydrogen g

Elenna [48]

This is an incomplete question, here is a complete question.

Suppose we now collect hydrogen gas, H₂(g), over water at 21°C in a vessel with total pressure of 743 Torr. If the hydrogen gas is produced by the reaction of aluminum with hydrochloric acid:

$2Al(s)+6HCl(aq)\rightarrow 2AlCl_3(aq)+3H_2(g)$

what volume of hydrogen gas will be collected if 1.35 g Al(s) reacts with excess HCl(aq)? Express your answer in liters.

Answer : The volume of hydrogen gas that will be collected is 1.85 L

Explanation :

First we have to calculate the number of moles of aluminium.

Given mass of aluminium = 1.35 g

Molar mass of aluminium = 27 g/mol

$\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}$

$\text{Moles of aluminium}=\frac{1.35g}{27g/mol}=0.05mol$

The given chemical reaction is:

$2Al(s)+6HCl(aq)\rightarrow 2AlCl_3(aq)+3H_2(g)$

As, hydrochloric acid is present in excess. So, it is considered as an excess reagent.

Thus, aluminium is a limiting reagent because it limits the formation of products.

By Stoichiometry of the reaction:

2 moles of aluminium produces 3 moles of hydrogen gas

So, 0.005 moles of aluminium will produce = $\frac{3}{2}\times 0.05=0.0750mol$ of hydrogen gas

Now we have to calculate the mass of helium gas by using ideal gas equation.

PV = nRT

where,

P = Pressure of hydrogen gas = 743 Torr

V = Volume of the helium gas = ?

n = number of moles of hydrogen gas = 0.075 mol

R = Gas constant = $62.364\text{ L Torr }mol^{-1}K^{-1}$

T = Temperature of hydrogen gas = $21^oC=[21+273]K=294K$

Now put all the given values in above equation, we get:

$743Torr\times V=0.075mol\times 62.364\text{ L Torr }mol^{-1}K^{-1}\times 294K\\\\V=1.85L$

Hence, the volume of hydrogen gas that will be collected is 1.85 L

8 0

3 years ago

Lead forms two compounds with oxygen. One contains 2.98g of lead and 0.461g of oxygen. The other contains 9.89g of lead and 0.76

aliina [53]

The given question is incomplete, the complete question is:

Lead forms two compounds with oxygen. One contains 2.98g of lead and 0.461g of oxygen. The other contains 9.89g of lead and 0.763g of oxygen. For a given mass of oxygen, what is the lowest whole-number mass ratio of lead in the two compounds that combines with a given mass of oxygen?

Answer:

The lowest whole-number mass ratio in the two compounds is 1:2.

Explanation:

There is a need to find the mole ratio between lead and oxygen atoms in order to find the whole-number mass ratio of lead in the two compounds. In the first compound, the given mass of lead is 2.98 grams, the molar mass of lead is 207.2 gram per mole.

The no. of moles can be determined by using the formula,

moles = mass/molecular mass

moles = 2.98 g/207.2 g/mol

= 0.0144 moles

The mass of oxygen in the compound I is 0.461 grams, the molecular mass of oxygen is 16 gram per mol.

moles = 0.461 g /16 g/mol

= 0.0288 moles

The ratio between the lead and oxygen in the compound I is 0.0144/0.0288 = 1:2

On the other hand, in the compound II, the mass of lead given is 9.89 grams, therefore, the moles of lead in compound II is,

moles = 9.89 g / 207.2 g/mol

= 0.0477 moles

The mass of oxygen given in compound II is 0.763 grams, the moles of oxygen present in the compound II is,

moles = 0.763 g / 16 g

= 0.0477 moles

The ratio between the lead and oxygen in the compound II is, 0.0477 moles lead /0.0477 moles oxygen = 1:1

Hence, of the two compounds, the lowest ratio is found in the compound I, that is, 1:2.

4 0

3 years ago