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Hitman42 [59]
2 years ago
7

What is the maximum mass, in kilograms, of (NH4)2U2O7 that can be formed from the reaction of 100 kg of water and 100 kg of ammo

nia with 481 kg of UO2SO4?
Chemistry
1 answer:
V125BC [204]2 years ago
5 0

Mass of (NH₄)₂U₂O₇ : 410.05 kg

<h3>Further explanation</h3>

Reaction

2UO₂SO₄ + 6NH₃ + 3H₂O → (NH₄)₂U₂O₇ + 2(NH₄)₂SO₄

MW UO₂SO₄ :  366.091

MW (NH₄)₂U₂O₇ : 624.131

MW H₂O :  18.0153

MW NH₃ : 17.0306

mol of 100 kg water :

\tt \dfrac{100}{18.0153}=5.55

mol of 100 kg ammonia :

\tt \dfrac{100}{17.036}=5.87

mol of UO₂SO₄ :

\tt \dfrac{481}{366.091}=1.314

Limiting reactants : smallest mol ratio(mol : coefficient)

\tt \dfrac{5.55}{3}\div \dfrac{5.87}{6}\div \dfrac{1.314}{2}=1.85\div 0.98\div 0.657

UO₂SO₄ ⇒ Limiting reactants

mol (NH₄)₂U₂O₇ : mol UO₂SO₄

\tt \dfrac{1}{2}\times 1.314=0.657

mass (NH₄)₂U₂O₇

\tt 0.657\times 624.131=410.05

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<u>Answer:</u> The amount of heat released is -7.203 kJ

<u>Explanation:</u>

The given chemical equation follows:

2H_2O_2(l)\rightarrow 2H_2O(l )+O_2(g);\Delta H=-196kJ

To calculate the enthalpy change for 1 mole of the hydrogen peroxide, we use unitary method:

When 2 moles of hydrogen peroxide is reacted, the enthalpy of the reaction is -196 kJ

So, when 1 mole of hydrogen peroxide will react, the enthalpy of the reaction will be \frac{-196}{2}\times 1=-98kJ

  • To calculate the number of moles, we use the equation:

\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}

Given mass of hydrogen peroxide = 2.50 g

Molar mass of hydrogen peroxide = 34 g/mol

Putting values in above equation, we get:

\text{Moles of hydrogen peroxide}=\frac{2.50g}{34g/mol}=0.0735mol

  • To calculate the heat of the reaction, we use the equation:

\Delta H_{rxn}=\frac{q}{n}

where,

q = amount of heat released

n = number of moles = 0.0735 moles

\Delta H_{rxn} = enthalpy change of the reaction = -98 kJ/mol

Putting values in above equation, we get:

-98kJ/mol=\frac{q}{0.0735mol}\\\\q=(-98kJ/mol\times 0.0735mol)=-7.203kJ

Hence, the amount of heat released is -7.203 kJ

8 0
3 years ago
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