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Hitman42 [59]
3 years ago
7

What is the maximum mass, in kilograms, of (NH4)2U2O7 that can be formed from the reaction of 100 kg of water and 100 kg of ammo

nia with 481 kg of UO2SO4?
Chemistry
1 answer:
V125BC [204]3 years ago
5 0

Mass of (NH₄)₂U₂O₇ : 410.05 kg

<h3>Further explanation</h3>

Reaction

2UO₂SO₄ + 6NH₃ + 3H₂O → (NH₄)₂U₂O₇ + 2(NH₄)₂SO₄

MW UO₂SO₄ :  366.091

MW (NH₄)₂U₂O₇ : 624.131

MW H₂O :  18.0153

MW NH₃ : 17.0306

mol of 100 kg water :

\tt \dfrac{100}{18.0153}=5.55

mol of 100 kg ammonia :

\tt \dfrac{100}{17.036}=5.87

mol of UO₂SO₄ :

\tt \dfrac{481}{366.091}=1.314

Limiting reactants : smallest mol ratio(mol : coefficient)

\tt \dfrac{5.55}{3}\div \dfrac{5.87}{6}\div \dfrac{1.314}{2}=1.85\div 0.98\div 0.657

UO₂SO₄ ⇒ Limiting reactants

mol (NH₄)₂U₂O₇ : mol UO₂SO₄

\tt \dfrac{1}{2}\times 1.314=0.657

mass (NH₄)₂U₂O₇

\tt 0.657\times 624.131=410.05

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The powder mixture (Cu, Al and Fe) = 10g was oxidized from sufficient chloride acid. 1) What are the possible reactions to the p
Mandarinka [93]

Answer:

1) 2Al + 6HCl ⟶ 2AlCl₃ + 3H₂

    Fe + 2HCl ⟶ FeCl₂ + H₂

2) Cu = 2.5 g; Al = 3.5 g; Fe = 4.0 g  

Explanation:

1) Possible reactions

2Al + 6HCl ⟶ 2AlCl₃ + 3H₂

Fe + 2HCl ⟶ FeCl₂ + H₂

2) Mass of each metal

a) Mass of Cu

The waste was the unreacted copper.

Mass of Cu = 2.5 g

b) Masses of Al and Fe

We have two relations :

Mass of Al + mass of Fe = 10 g - 2.5 g = 7.5 g

H₂ from Al + H₂ from Fe = 6.38 L at NTP

i) Calculate the moles of H₂

NTP is 20 °C and 1 atm.

\begin{array}{rcl}pV & = & n RT\\\text{1 atm} \times \text{6.38 L} & = & n \times 0.08206 \text{ L}\cdot\text{atm}\cdot\text{K}^{-1}\text{mol}^{-1} \times \text{293.15 K}\\6.38 & = & 24.06n \text{ mol}^{-1} \\n & = & \dfrac{6.38}{24.06 \text{ mol}^{-1} }\\\\ & = & \text{0.2652 mol}\\\end{array}

(ii) Solve the relationship

 Let x = mass of Al. Then

7.5 - x = mass of Fe

Moles of Al = x/27

Moles of Fe = (7.5 - x)/56

Moles of H₂ from Al = (3/2) × Moles of Al = (3/2) × (x/27) = x /18

Moles of H₂ from Fe = (1/1) × Moles of Fe = (7.5 - x)/56

∴ x/18 + (7.5 - x)/56 = 0.2652

    56x + 18(7.5 - x) = 267.3

      56x + 135 - 18x = 267.3

                        38x = 132.3

                            x = 3.5 g

Mass of Al = 3.5 g

Mass of Fe = 7.5 g - 3.5 g = 4.0 g

The masses of the metals are Cu = 2.5 g; Al = 3.5 g; Fe = 4.0 g

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