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Veseljchak [2.6K]
2 years ago
7

Student carries out a titration to determine the concentration of a solution of

Chemistry
1 answer:
Nimfa-mama [501]2 years ago
7 0

The concentration of the Nitric acid solution : 0.114 M

<h3>Further explanation  </h3>

Titration is a procedure for determining the concentration of a solution (analyte) by reacting with another solution whose known concentration (usually a standard solution) is called the titrant. Determination of the endpoint/equivalence point of the reaction can use indicators according to the appropriate pH range  

Titrations can be acid-base titration, depositional titration, and redox titration. An acid-base titration is the principle of neutralization of acids and bases  

Reaction

HNO₃ + NaOH → NaNO₃ + H₂O​

Concentration a standard solution  of sodium hydroxide :  0.0998 mol/dm³ , and the volume = 25 cm³

moles NaOH=

\tt mol=M\times V\\\\mol=0.0998\times 25\\\\mol=2.495~mlmoles

<em>From the equation, mol ratio HNO₃ : NaOH = 1 : 1, so mol HNO₃ = mol NaOH=</em><em>2.495 mlmoles</em>

<em></em>

The volume of HNO₃ = 21.8 cm³, so the concentration :

\tt M=\dfrac{n}{V}\\\\M=\dfrac{2.495}{21.8}\\\\M=0.114

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Answer:

The answer is 5.7 minutes

Explanation:

A first-order reaction follow the law of Ln [A] = -k.t + Ln [A]_{0}. Where <em>[A]</em> is the concentration of the reactant at any <em>t</em> time of the reaction, [A]_{0} is the concentration of the reactant at the beginning of the reaction and <em>k</em> is the rate constant.

Dropping the concentration of the reactant to 6.25% means the concentration of A at the end of the reaction has to be [A]=\frac{6.25}{100}.[A]_{0}. And the rate constant (<em>k</em>) is 8.10×10−3 s−1

Replacing the equation of the law:

Ln \frac{6.25}{100}.[A]_{0} = -8.10x10^{-3}s^{-1}.t + Ln[A]_{0}

Clearing the equation:

Ln [A]_{0}.\frac{6.25}{100} - Ln [A]_{0} = -8.10x10^{-3}s^{-1}.t

<em>Considering the property of logarithms: </em>Ln A - Ln B = Ln \frac{A}{B}

Using the property:

Ln \frac{[A]_{0}}{[A]_{0}}.\frac{6.25}{100} = -8.10x10^{-3}s^{-1}.t

Clearing <em>t </em>and solving:

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The answer is in the unit of seconds, but every minute contains 60 seconds, converting the units:

342.3x\frac{1min}{60s} = 5.7min

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